25772-85-4

Basic information

• Product Name: 2-Propanol, 1-chloro-3-(4-methoxyphenoxy)-
• CAS NO: 25772-85-4
• Molecular Formula: C10H13ClO3
• Molecular Weight: 216.664
• Mol File: 25772-85-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-Propanol, 1-chloro-3-(4-methoxyphenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanol, 1-chloro-3-(4-methoxyphenoxy)-(25772-85-4)
• EPA Substance Registry System: 2-Propanol, 1-chloro-3-(4-methoxyphenoxy)-(25772-85-4)

Safety Data

• Hazardous Substances Data: 25772-85-4(Hazardous Substances Data)

Upstream product

• 150-76-5 4-methoxy-phenol 
• 106-89-8 epichlorohydrin 
• 2211-94-1 2,3-epoxypropyl p-methoxyphenyl ether 

Downstream Products

• 141987-52-2 Acetic acid (S)-1-chloromethyl-2-(4-methoxy-phenoxy)-ethyl ester 
• 142037-06-7 (R)-1-Chloro-3-(4-methoxy-phenoxy)-propan-2-ol 
• 140647-18-3 Acetic acid (R)-1-chloromethyl-2-(4-methoxy-phenoxy)-ethyl ester 
• 2211-94-1 4-methoxybenzyloxy ester of (S)-glycidol 
• 2211-94-1 (2S)-2-{[4-(methoxy)phenoxy]methyl}oxirane 
• 142036-87-1 Acetic acid 1-chloromethyl-2-(4-methoxy-phenoxy)-ethyl ester 
• 140696-03-3 (S)-1-chloro-3-(4-methoxyphenoxy)-2-propanol 

Relevant articles and documents

A phosphonium ylide as a visible light organophotoredox catalyst

A phosphonium ylide-based visible light organophotoredox catalyst has been designed and successfully applied to halohydrin synthesis using trichloroacetonitrile and epoxides. An oxidative quenching cycle by the ylide catalyst was established, which was confirmed by experimental mechanistic studies.

Protective opening of epoxide using pivaloyl halides under catalyst-free conditions

An efficient and environmentally benign protocol for protective opening of epoxide (POE) with pivaloyl halides in solvent-free conditions and in aqueous media under catalyst-free conditions has been developed. The green reaction conditions, simple work-up procedures, high yields and broad scope of the reaction illustrate the good synthetic utility of this method. The key advantages of the reaction are regioselectivity and reconvertability of products into their prior epoxides in the presence of mild reaction conditions.

Ionic liquid as reagent. A green procedure for the regioselective conversion of epoxides to vicinal-halohydrins using [AcMIm]X under catalyst- and solvent-free conditions

A variety of structurally diverse epoxides undergo facile cleavages by ionic liquid, [AcMIm]X without any catalyst and solvent to produce the corresponding vicinal halohydrins in high yields. The cleavages are considerably fast and highly regioselective.