26086-06-6

Basic information

• Product Name: Phosphinic acid, phenyl(phenylmethyl)-, methyl ester
• CAS NO: 26086-06-6
• Molecular Formula: C14H15O2P
• Molecular Weight: 246.246
• Mol File: 26086-06-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Phosphinic acid, phenyl(phenylmethyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphinic acid, phenyl(phenylmethyl)-, methyl ester(26086-06-6)
• EPA Substance Registry System: Phosphinic acid, phenyl(phenylmethyl)-, methyl ester(26086-06-6)

Safety Data

• Hazardous Substances Data: 26086-06-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 20335-99-3 benzyl (phenyl)phosphine oxide 
• 1445-45-0 Trimethyl orthoacetate 
• 7282-98-6 (±)-benzyl(phenyl)phosphinic acid 
• 2946-61-4 phenylphosphonous acid dimethyl ester 
• 100-39-0 benzyl bromide 

Downstream Products

• 609-72-3 N,N-dimethyl-o-toluidine 
• 7282-98-6 (±)-benzyl(phenyl)phosphinic acid 
• 611-21-2 N,2-dimethylaniline 

Relevant articles and documents

Dynamic Kinetic Resolution of Phosphinic Acid Derivatives via Nucleophilic Substitution at Phosphorus Center

Reaction of racemic phosphinic acid derivatives with chiral alcohols proceeds with predominant formation of one diastereomer. The highest level of enrichment has been obtained for transesterfication of racemic methyl benzylphenylphosphinate (64% de). The

Facile preparation of polymer-supported methyl sulfonate and its recyclable use for methylation of carboxylic acids and amines

A simple and efficient one-pot procedure for the preparation of polymer-supported methyl sulfonate from the reaction of polymer-supported sulfonic acid with trimethyl orthoacetate was achieved, and it could be successfully used for efficient methylation of carboxylic acids, phosphonic acids, sulfinic acids, amines, thiol, and phenol. Moreover, the polymer reagent could be recovered, regenerated, and reused easily for the same reactions. Georg Thieme Verlag Stuttgart.