50487-72-4Relevant articles and documents
Immobilisation of an ionically tagged Hoveyda catalyst on a supported ionic liquid membrane: An innovative approach for metathesis reactions in a catalytic membrane reactor
Keraani,Rabiller-Baudry,Fischmeister,Bruneau
, p. 268 - 275 (2010)
This study aimed at developing an innovative strategy to recycle homogeneous olefin metathesis catalysts by the combination of complementary green processes, namely organic solvent nanofiltration coupled with ionic liquid advantages. The immobilisation of
One-pot chemoenzymatic reactions in water enabled by micellar encapsulation
Adams, Nicholas P.,Bushi, Jurgen,Hastings, Courtney J.,Kolb, Samuel J.
supporting information, p. 6187 - 6193 (2020/10/18)
The use of micellar conditions to enable one-pot reactions involving both transition metal and enzymatic catalysts is reported. Representative enzymatic transformations under micellar conditions are unaffected by the presence of non-ionic surfactants, including designer surfactants such as TPGS-750-M. Furthermore, the presence of enzymes has a negligible effect on transition metal catalysis under micellar conditions in water. Finally, three one-pot chemoenzymatic reactions in water are reported in which the micelle-forming surfactant TPGS-750-M is a crucial factor for reaction efficiency.
Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes Mediated by a Metastable Charge-Transfer Complex
Siu, Juno C.,Parry, Joseph B.,Lin, Song
supporting information, p. 2825 - 2831 (2019/02/14)
We report the development of a new aminoxyl radical catalyst, CHAMPO, for the electrochemical diazidation of alkenes. Mediated by an anodically generated charge-transfer complex in the form of CHAMPO-N3, radical diazidation was achieved across a broad scope of alkenes without the need for a transition metal catalyst or a chemical oxidant. Mechanistic data support a dual catalytic role for the aminoxyl serving as both a single-electron oxidant and a radical group transfer agent.