505-29-3Relevant articles and documents
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Bennett,Berry
, p. 910 (1925)
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REACTION OF DIHALOALKANES WITH INORGANIC SULFIDES
Rafikov, S. R.,Aleev, R. S.,Masagutov, R. M.,Dobrikov, A. L.,Komissarov, V. D.
, (1982)
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Enhanced thermal degradation of 2,2′-dichlorodiethyl sulfide (sulfur mustard, HD) with the presence of metal oxides
Jung, Hyunsook,Lee, Hae Wan,Jeong, Eun Ah
, p. 1137 - 1141 (2016/07/27)
Thermal degradation of sulfur mustard (2,2′-dichlorodiethyl sulfide, HD) in the presence of metal oxide adsorbents was investigated by thermal desorption in conjunction with gas chromatography–mass spectrometry (GC-MS). Zr(OH)4, Al2O3, Al2CoO4, MgO, CeO2, and V2O5were used as metal oxide adsorbents. Neat HD was spiked onto the metal oxides packed in glass tubes, which were kept at room temperature and then heated at moderately elevated temperatures of 100°C by a thermal desorption system. The products of thermal degradation were directly transferred and analyzed by GC-MS. 1,4-Dithiane and 1,4-oxathiane were characterized as the major products of the thermal degradation of HD in the presence of Zr(OH)4, Al2O3, Al2CoO4, and CeO2adsorbents. No effective degradation was observed with MgO and V2O5. Of particular note is Zr(OH)4, which extremely enhanced the thermal degradation of HD.
A highly efficient carbon-sulfur bond formation reaction via microwave-assisted nucleophilic substitution of thiols to polychloroalkanes without a transition-metal catalyst
Cao, Yi-Ju,Lai, Yuan-Yuan,Cao, Hong,Xing, Xiao-Ning,Wang, Xiang,Xiao, Wen-Jing
, p. 1529 - 1533 (2007/10/03)
An efficient carbon-sulfur bond formation reaction has been developed under microwave irradiation. This reaction affords a novel and rapid synthesis of thioacetals and sulfides under mild conditions. This method is particularly noteworthy given its experimental simplicity and high generality, and no transition-metal catalysts were needed under our conditions.
Synthetic potentialities of sulfonylsulfonium salts: A new approach to the preparation of disulfonium dications
Shevchenko,Nenaidenko,Balenkova
, p. 1415 - 1420 (2007/10/03)
A new efficient method for the generation of disulfonium dications whose subsequent hydrolysis selectively affords monosulfoxides was developed based on the oxidation of bis-sulfides by trifluoromethanesulfonic anhydride.