7521-41-7Relevant articles and documents
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Majewicz,Caluwe
, p. 720 (1974)
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Highly efficient synthesis of 2-amino-3-pyridinecarboxaldehyde
Rivera,Hsiao,Cowen,McWilliams,Armstrong,Yasuda,Hughes
, p. 1573 - 1579 (2001)
2-Amino-3-pyridinecarboxaldehyde is synthesized in a highly efficient process via ortho-lithiation of 2-(pivaloyl-amino)pyridine and reaction with DMF, followed by acid hydrolysis. Major impurities were identified and were cleanly eliminated through careful choice of base and solvent.
A dual-model and on-off fluorescent Al3+/Cu2+- chemosensor and the detection of F-/Al3+ with 'in situ' prepared Al3+/Cu2+ complexes
Li, Xiaoya,Yu, Mingming,Yang, Faliu,Liu, Xingjiang,Wei, Liuhe,Li, Zhanxian
, p. 2257 - 2260 (2013)
A multifunctional fluorescent chemosensor for Al3+ and Cu 2+ has been developed, which displays a dual-model and on-off fluorescence response upon addition of Al3+ and Cu2+ respectively. The fluorescence signals of the chemosensor can be restored with F- and ethylenediaminetetraacetic acid (EDTA) disodium for Al 3+ and Cu2+, showing that the binding of the chemosensor and Al3+/Cu2+ is chemically reversible. The 'in situ' prepared Al3+ complex (1·Al) showed high selectivity toward F-, which can be applied to distinguish F- from Cl -, Br- and I-. Moreover, the fluorescence emission intensity of the 'in situ' prepared Cu2+ complex (1·Cu) is increased with the addition of Al3+, demonstrating that 1·Cu could be a good off-on Al3+ sensor candidate.
Diruthenium complexes with a 1,8-Naphthyridine-based Bis(silyl) supporting ligand: Synthesis and structures of complexes containing RuII2(μ-H)2 and RuI2 cores
Kusuma, Indra,Komuro, Takashi,Tobita, Hiromi
, p. 400 - 403 (2018/03/27)
We designed a novel naphthyridine-based supporting ligand involving two silyl coordinating moieties at 2,7-positions, t-BuNBSi, for the synthesis of dinuclear metal complexes. Reaction of a ligand precursor t-BuNBSi(H)2 (1) with Ru3(CO)12 gave a di-μ-hydridodiruthenium(II,II) complex (t-BuNBSi)Ru2(μ-H)2(CO)4 (2). Photoirradiation to 2 resulted in the formation of a diruthenium(I,I) complex (t-BuNBSi)Ru2(CO)6 (3). The SiRuRuSi linkage of 2 takes a zigzag arrangement, whereas that of 3 adopts a roughly linear one.
A formaldehyde fast detection reagent and its preparation method and application
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Paragraph 0033; 0035; 0038; 0039, (2017/07/04)
The invention discloses a formaldehyde quick detection reagent, a preparation method and an application thereof. A chemical name of the formaldehyde quick detection reagent is 2-amino-3-(3-amino-1H-benzo[d]imidazole)-pyridine of which a chemical structure formula is represented as the formula I. The preparation method comprises following steps: (1) carrying out a reaction to a mixture consisting of nicotinamide and ammonium sulfamate in oil bath at 200 DEG C for 6 hours to obtain an intermediate 3; (2) performing temperature-increasing reflux to the intermediate 3 in an acid environment for 4 hours, cooling the intermediate 3 to room temperature and adjusting the pH value to 7-8 to obtain an intermediate 2; and (3) carrying out a reaction to the intermediate 2 with 1,2,4-triaminobenzene to obtain a target product. The reagent prepared according to the method hereinbefore can quite easily detect the concentration of formaldehyde. The formaldehyde quick detection reagent is simple in synthetic route, is low in cost, is convenient to use, is suitable for actual production application, is high in probe responding speed and is high in sensitivity. The reagent can achieve quick detection quantitatively and high-sensitively of the formaldehyde in environment and foods.