77291-92-0

Basic information

• Product Name: 1,3-Propanediol, 1,3-diphenyl-, (1R,3R)-
• Synonyms: (+)-(R,R)-1,3-diphenyl-1,3-propanediol;anti-(R,R)-1,3-diphenyl-1,3-propanediol;(1R,3R)-1,3-Diphenyl-1,3-propanediol;(R,R)-(+)-1,3-diphenylpropane-1,3-diol;(1R,3R)-1,3-Diphenyl-propane-1,3-diol;(R,R)-1,3-diphenylpropane-1,3-diol;(1R,3R)-1,3-diphenylpropane-1,3-diol
• CAS NO: 77291-92-0
• Molecular Formula: C15H16O2
• Molecular Weight: 228.291
• Mol File: 77291-92-0.mol
• Article Data: 54

Chemical Properties

• CAS DataBase Reference: 1,3-Propanediol, 1,3-diphenyl-, (1R,3R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Propanediol, 1,3-diphenyl-, (1R,3R)-(77291-92-0)
• EPA Substance Registry System: 1,3-Propanediol, 1,3-diphenyl-, (1R,3R)-(77291-92-0)

Safety Data

• Hazardous Substances Data: 77291-92-0(Hazardous Substances Data)

Upstream product

• 67210-34-8 1-phenyl-2-phenylsulfanyl-ethanol 
• 100-52-7 benzaldehyde 
• 120-46-7 1,3-diphenylpropanedione 
• 29881-14-9 1,2-diphenyl-cyclopropane 
• 96-09-3 styrene oxide 
• 72237-28-6 (R)-(+)-3-acetoxy-3-phenylpropiophenone 
• 101597-24-4 3-acetoxy-1,3-diphenylpropan-1-one 
• 60-29-7 diethyl ether 
• 62961-62-0 (Z)-3-hydroxy-1,3-diphenyl-2-propen-1-one 
• 24168-52-3 1,2-Diphenylcyclopropen 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 1138-47-2 trans-1,2-diphenylcyclopropane 
• 98-86-2 acetophenone 
• 886-38-4 diphenylcyclopropenone 

Downstream Products

• 26278-69-3 1,3-diphenyl-1,3-dimethoxy propane 
• 7107-24-6 1,3-diphenyl-1-methoxy-3-hydroxy propane 
• 120-46-7 1,3-diphenylpropanedione 
• 17714-40-8 1,3-Dibromo-1,3-diphenylpropane 
• 108391-15-7 (1S,3S)-1,3-diphenylpropane-1,3-diol 
• 59132-37-5 (+)-(1S,3S)-1,3-diphenyl-1,3-propanediamine 
• 229018-03-5 (-)-(S,S)-1,3-diphenyl-1,3-propanediazide 
• 19293-52-8 racemic 1,3-diphenyl-1,3-propanediamine 
• 135614-40-3 (1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine 
• 135613-89-7 (1R^*,3R^*)-N,N'-dibenzyl-1,3-diphenyl-1,3-propanediamine 

Relevant articles and documents

Reductive Ring-Opening 1,3-Difunctionalizations of Arylcyclopropanes with Sodium Metal

Sodium dispersion promotes reductive ring opening of arylcyclopropanes. The presence of a reduction-resistant electrophile, such as methoxypinacolatoborane, epoxide, oxetane, paraformaldehyde, or chlorotrimethylsilane, during the reductive ring opening event leads to the formation of 1,3-difunctionalized 1-arylalkanes by immediate trappings of the resulting two reactive carbanions. In particular, the ring-opening 1,3-diborylations of arylcyclopropanes afford 1,3-diborylalkanes with high syn selectivity.

NOVEL PHOSPHOROUS (V)-BASED REAGENTS, PROCESSES FOR THE PREPARATION THEREOF, AND THEIR USE IN MAKING STEREO-DEFINED ORGANOPHOSHOROUS (V) COMPOUNDS

The present invention relates to novel phosphorous (V) (P(V)) reagents, methods for preparing thereof, and methods for preparing organophosphorous (V) compounds by using the novel reagents.

Double Catalytic Kinetic Resolution (DoCKR) of Acyclic anti-1,3-Diols: The Additive Horeau Amplification

The concept of a synergistic double catalytic kinetic resolution (DoCKR) as described in this article was successfully applied to racemic acyclic anti-1,3-diols, a common motif in natural products. This process takes advantage of an additive Horeau amplif