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791785-35-8

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791785-35-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 791785-35-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 7,9,1,7,8 and 5 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 791785-35:
(8*7)+(7*9)+(6*1)+(5*7)+(4*8)+(3*5)+(2*3)+(1*5)=218
218 % 10 = 8
So 791785-35-8 is a valid CAS Registry Number.

791785-35-8Relevant articles and documents

Transformation of Thiolatogold(I) to an Au Complex with an (Arylthio)silyl Ligand. Use of an (Aminosilyl)boronic Ester as a Silylene Precursor

Tsuchido, Yoshitaka,Okuma, Kazuki,Osakada, Kohtaro,Ide, Tomohito

, p. 2565 - 2569 (2020)

The gold(I) thiolate complex [Au(SC6H4-4-OMe)(PCy3)] reacts with an (aminosilyl)boronic ester, Et2N-SiPh2-BO(CMe2)2O, to afford a complex with an (arylthio)silyl ligand, [Au(SiPh2(SC6H4-4-OMe))(PCy3)]. In the solid state the molecule shows almost linear Si-AuI-P coordination. DFT studies revealed that the reaction pathway involves an intermediate having an Au-S bond formed via initial association of the Si center of the substrate with the thiolate ligand. Reaction of H2SiPh2 with the thiolate complex also produces the silylgold complex in a lower yield.

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