Basic Information | Post buying leads | Suppliers | Cas Database |
Name |
(Allyloxy)(tert-butyl)dimethylsilane |
EINECS | N/A |
CAS No. | 105875-75-0 | Density | 0.804 g/cm3 |
PSA | 9.23000 | LogP | 3.19420 |
Solubility | Sparingly soluble in water (0.50 g/L at 25°C). | Melting Point |
N/A |
Formula | C9H20OSi | Boiling Point | 165.9 °C at 760 mmHg |
Molecular Weight | 172.343 | Flash Point | 44.2 °C |
Transport Information | UN 1993 3/PG 3 | Appearance | N/A |
Safety | 16 | Risk Codes | 10 |
Molecular Structure | Hazard Symbols | N/A | |
Synonyms |
ALLYLOXY-T-BUTYLDIMETHYLSILANE;ALLYLOXY-TERT-BUTYLDIMETHYLSILANE;ALLYLOXY-TERT-BUTYLDIMETHYLSILANE 97%;1-[(1,1-Dimethylethyl)dimethylsilyl]-2-propen-1-ol;1-(tert-ButyldiMethylsilyl)prop-2-en-1-ol |
Article Data | 8 |
The 2-Propen-1-ol,1-[(1,1-dimethylethyl)dimethylsilyl]- is an organic compound with the formula C9H20OSi. The IUPAC name of this chemical is dimethyl-(2-methyl-1-prop-2-enoxypropan-2-yl)silicon. With the CAS registry number 105875-75-0, it is also named as Allyloxy-tert-butyldimethylsilane. The product's categories are Acyclic; Alkenes; Organic Building Blocks. Besides, it should be stored in a closed cool and dry place.
Physical properties about 2-Propen-1-ol,1-[(1,1-dimethylethyl)dimethylsilyl]- are: (1)ACD/LogP: 3.68; (2)ACD/LogD (pH 5.5): 3.67; (3)ACD/LogD (pH 7.4): 3.67; (4)ACD/BCF (pH 5.5): 365.55; (5)ACD/BCF (pH 7.4): 365.55; (6)ACD/KOC (pH 5.5): 2377.71; (7)ACD/KOC (pH 7.4): 2377.71; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 4; (10)Polar Surface Area: 9.23 Å2; (11)Index of Refraction: 1.416; (12)Molar Refractivity: 53.89 cm3; (13)Molar Volume: 214.3 cm3; (14)Polarizability: 21.36×10-24cm3; (15)Surface Tension: 19.9 dyne/cm; (16)Density: 0.804 g/cm3; (17)Flash Point: 44.2 °C; (18)Enthalpy of Vaporization: 38.58 kJ/mol; (19)Boiling Point: 165.9 °C at 760 mmHg; (20)Vapour Pressure: 2.41 mmHg at 25°C.
Preparation: this chemical can be prepared by tert-butyl-chloro-dimethyl-silane and prop-2-en-1-ol. This reaction will need reagent Et3N, DMAP and solvent CH2Cl2. The reaction time is 2 hours with reaction temperature of 25 °C.
Uses of 2-Propen-1-ol,1-[(1,1-dimethylethyl)dimethylsilyl]-: it can be used to produce 2-tert-butyldimethylsilyloxy-acetaldehyde at temperature of 23 °C. It will need reagent NaIO4, OsO4 and solvent diethyl ether, H2O, 2-methyl-propan-2-ol with reaction time of 2 hours. The yield is about 42%.
You can still convert the following datas into molecular structure:
(1)SMILES: O(C\C=C)[Si](C(C)(C)C)(C)C
(2)InChI: InChI=1/C9H20OSi/c1-7-8-10-11(5,6)9(2,3)4/h7H,1,8H2,2-6H3
(3)InChIKey: DHWVPYLVNAKSEU-UHFFFAOYAY
(4)Std. InChI: InChI=1S/C9H20OSi/c1-7-8-10-11(5,6)9(2,3)4/h7H,1,8H2,2-6H3
(5)Std. InChIKey: DHWVPYLVNAKSEU-UHFFFAOYSA-N