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Name	2,4-Dichlorobenzoyl peroxide	EINECS	205-094-9
CAS No.	133-14-2	Density	1.577 g/cm³
PSA	52.60000	LogP	5.22900
Solubility	29.93μg/L at 25℃	Melting Point	55 °C (dec.)
Formula	C₁₄H₆Cl₄O₄	Boiling Point	487.2 °C at 760 mmHg
Molecular Weight	380.011	Flash Point	194.1 °C
Transport Information	UN 3106	Appearance	white paste
Safety	15-17	Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	2,4-Dichlorobenzoylperoxide;2,4-Dichlorobibenzoyl peroxide;Bis(2,4-dichlorobenzoyl) peroxide;C 2 (crosslinking agent);Cadox TDP;Cadox TS;Cadox TS 50;Chaloxyd DCLBP50PSI;Elastosil AUX Crosslinker E;Elastosil AUX-E;Perkadox PD 50S;Siloprene CL 40;TC 2;TC 2 (peroxide);o,o',p,p'-Tetrachlorodibenzoyl peroxide;Vulcanizing agent DCBP;

2,4-Dichlorobenzoyl peroxide Synthetic route

: 89-75-8
2,4-dichlorobenzoyl chloride

: 133-14-2
bis(2,4-dichlorobenzoyl)-peroxide

Conditions

Conditions	Yield
With (2S)-N-methyl-1-phenylpropan-2-amine hydrate; sodium peroxide; acetone

: 609-65-4
o-chlorobenzoyl chloride

: 89-75-8
2,4-dichlorobenzoyl chloride

A: 133-14-2
bis(2,4-dichlorobenzoyl)-peroxide

B: 1198794-83-0
2-chlorobenzoyl 2,4-dichlorobenzoyl peroxide

Conditions

Conditions	Yield
With dihydrogen peroxide; sodium hydroxide In water at 20℃; for 0.5h; Product distribution / selectivity;

: 119072-55-8, 7188-38-7
tert-butylisonitrile

: 133-14-2
bis(2,4-dichlorobenzoyl)-peroxide

: 61176-08-7
N-(tert-butyl)-2,4-dichlorobenzamide

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide In water at 120℃; for 12h; Sealed tube;	78%

: 133-14-2
bis(2,4-dichlorobenzoyl)-peroxide

: 2437-79-8
2,2',4,4'-Tetrachlorobiphenyl

Conditions

Conditions	Yield
Thermolysis.im Vakuum;

: 133-14-2
bis(2,4-dichlorobenzoyl)-peroxide

A: 50-84-0
2,4 dichlorobenzoic acid

B: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

C 2.4.2'.4'-tetrachloro-diphenyl: 2.4.2'.4'-tetrachloro-diphenyl

Conditions

Conditions	Yield
im Vakuum;

2,4-Dichlorobenzoyl peroxide Consensus Reports

Reported in EPA TSCA Inventory.

2,4-Dichlorobenzoyl peroxide Standards and Recommendations

DOT Classification: Forbidden

2,4-Dichlorobenzoyl peroxide Specification

The Bis(2,4-dichlorobenzoyl) peroxide, with the CAS registry number 133-14-2, is also known as Cadox TDP. Its EINECS registry number is 205-094-9. This chemical's molecular formula is C₁₄H₆Cl₄O₄ and molecular weight is 380.00704. Its IUPAC name is called (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate. When you are using this chemical, please be cautious about it. You should keep it away from heat and combustible material. What's more, this chemical is appropriate for open vulcanization of silicon rubber.

Physical properties of Bis(2,4-dichlorobenzoyl) peroxide: (1)ACD/LogP: 5.37; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 5.37; (4)ACD/LogD (pH 7.4): 5.37; (5)ACD/BCF (pH 5.5): 7126.33; (6)ACD/BCF (pH 7.4): 7126.33; (7)ACD/KOC (pH 5.5): 19928.39; (8)ACD/KOC (pH 7.4): 19928.39; (9)#H bond acceptors: 4; (10)#Freely Rotating Bonds: 5; (11)Index of Refraction: 1.617; (12)Molar Refractivity: 84.31 cm³; (13)Molar Volume: 240.9 cm³; (14)Surface Tension: 54.9 dyne/cm; (15)Density: 1.577 g/cm³; (16)Flash Point: 194.1 °C; (17)Enthalpy of Vaporization: 75.31 kJ/mol; (18)Boiling Point: 487.2 °C at 760 mmHg; (19)Vapour Pressure: 1.21E-09 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C1=CC(=C(C=C1Cl)Cl)C(=O)OOC(=O)C2=C(C=C(C=C2)Cl)Cl
(2)InChI: InChI=1S/C14H6Cl4O4/c15-7-1-3-9(11(17)5-7)13(19)21-22-14(20)10-4-2-8(16)6-12(10)18/h1-6H
(3)InChIKey: WRXCBRHBHGNNQA-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	225mg/kg (225mg/kg)		International Polymer Science and Technology. Vol. 3, Pg. 93, 1976.

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