Molecular Structure:
CAS No.:	121-46-0
Name:	2,5-Norbornadiene

Formula:	C₇H₈
Molecular Weight:	92.1405
Synonyms:	2,5-Norbornadiene(8CI);3,6-Methano-1,4-cyclohexadiene;Bicyclo[2.2.1]heptadiene;NSC 13672;Norbornadiene;Bicyclo[2.2.1]hepta-2,5-diene;
EINECS:	204-472-0
Density:	1.003 g/cm³
Melting Point:	-20--19 °C
Boiling Point:	89.5 °C at 760 mmHg
Flash Point:	12 °F
Solubility:	Immiscible with water.
Appearance:	Clear colorless to slightly yellow liquid
Hazard Symbols:	F
Risk Codes:	11
Safety:	16-23
Transport Information:	UN 2251 3/PG 2
PSA:	0.00000
LogP:	1.74850

Conditions	Yield
x In nitromethane at 25℃;	100%
cadmium(II) sulphide In dichloromethane for 3h; Product distribution; Irradiation; other semiconducters, presence of methylviologen dication and diphenylamine;	1.8%
3,3-dimethyldioxirane In dichloromethane; acetone at 0℃; for 0.0166667h;	60 % Turnov.

Conditions	Yield
With 1-Cyanonaphthalene In methanol Irradiation;
dichloro(norbornadiene)palladium(II) In dichloromethane at 25℃; for 1h; Product distribution; Quantum yield; Mechanism; Irradiation; different Q concentration, solvent, times, intensity and wavelenght of irradiation, effect of free radical scavenger;
With 9,10-Dicyanoanthracene In hexane Quantum yield; Mechanism; Rate constant; Ambient temperature; Irradiation; exciplex isomerization, var. of sensitizer, solv.;
With aluminum oxide; 4-Aminosalicylic acid; tetrasodium (5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinato)cobalt(II) In pentane at 24℃; Rate constant; Thermodynamic data; ΔH(activation);
With trichlorostannylacetylene at 25℃; for 1h; Inert atmosphere;

Conditions	Yield
With methanol; sodium dihydrogenphosphate; sodium amalgam Ambient temperature;	65%
With sodium dihydrogenphosphate; sodium amalgam In methanol Ambient temperature;	65%

Conditions	Yield
With 18-crown-6 ether; potassium tert-butylate In various solvent(s) at 60℃; Yield given. Yields of byproduct given;
With 18-crown-6 ether; potassium tri-2-norbornylmethoxide In various solvent(s) at 60℃; Yield given. Yields of byproduct given;

Conditions	Yield
With 9,10-Dicyanoanthracene Irradiation;
With 9,10-Dicyanoanthracene In acetonitrile at 23℃; Product distribution; Mechanism; Irradiation; var. sensitizers and solvents;
In various solvent(s) at 144.85℃; Kinetics; Further Variations:; Temperatures;

1.	orl-rat LD50:890 mg/kg SHELL*
2.	ihl-rat LC50:14,100 ppm/8H	SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
3.	ipr-rat LD50:890 mg/kg	SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
4.	orl-mus LD50:3850 mg/kg	SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
5.	ihl-mus LC50:27,700 ppm/30M	SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
6.	ivn-mus LD50:56 mg/kg	CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#04158 .

121-46-0