Basic Information | Post buying leads | Suppliers | Cas Database |
Conditions | Yield |
---|---|
With potassium fluoride; polymethylhydrosiloxane; palladium diacetate In tetrahydrofuran; water at 20℃; for 3h; | 100% |
With potassium fluoride; polymethylhydrosiloxane; palladium diacetate In tetrahydrofuran at 20℃; for 0.5h; | 100% |
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; for 10h; | 100% |
2,6-dimethylphenylazide
2,6-dimethylaniline
Conditions | Yield |
---|---|
With sodium hydrogen telluride In diethyl ether; ethanol for 0.25h; Ambient temperature; | 100% |
With aluminium(III) iodide In benzene for 0.166667h; Reduction; Heating; | 90% |
With diphosphorus tetraiodide In benzene for 11h; Heating; | 40% |
Conditions | Yield |
---|---|
With dichloro(dimethylglyoxime)(dimethylglyoximato)cobalt(III); (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; triethylamine In acetonitrile at -78℃; for 24h; Reagent/catalyst; Sealed tube; Inert atmosphere; Irradiation; | 100% |
Conditions | Yield |
---|---|
With sodium hydroxide In water at 60 - 130℃; under 4560.31 Torr; for 3.5h; Temperature; | 99.1% |
2,6-dimethylaniline
Conditions | Yield |
---|---|
With ethylenediamine In ethanol at 65℃; for 14h; | 99% |
Conditions | Yield |
---|---|
With 2-((dicyclohexylphosphino)methyl)-1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium iodide; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere; | 98% |
With C28H30Cl5N3Pd; ammonia; lithium isopropoxide; sodium t-butanolate In 1,4-dioxane at 100℃; for 2h; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 91% |
With bis(tri-ortho-tolylphosphine)palladium(0); (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl-di-tert-butylphosphine; ammonia; sodium t-butanolate In 1,4-dioxane at 100℃; for 24h; Inert atmosphere; | 89% |
Conditions | Yield |
---|---|
With potassium hydroxide In water at 60 - 125℃; under 2280.15 Torr; for 3h; | 97.5% |
1,2-dimethoxybenzene
N-(2,6-diimethylphenyl)benzamide
A
3,4-dimethoxybenzophenone
B
2,6-dimethylaniline
Conditions | Yield |
---|---|
Stage #1: N-(2,6-diimethylphenyl)benzamide With 2-fluoropyridine; trifluoromethylsulfonic anhydride In dichloromethane at -78 - 0℃; for 0.166667h; Inert atmosphere; Stage #2: 1,2-dimethoxybenzene In dichloromethane at 0 - 20℃; Inert atmosphere; Stage #3: With hydrogenchloride; water In ethanol for 2h; Inert atmosphere; Reflux; chemoselective reaction; | A 97% B 90% |
Conditions | Yield |
---|---|
With 2,6-dimethylcyclohexanone; ammonium hydroxide; 5%-palladium/activated carbon at 180℃; for 5h; Concentration; Temperature; | 95.62% |
With ammonia; hydrogen In 1,4-dioxane at 230℃; under 760.051 Torr; | 86.56% |
With ammonia |
2,6-dimethylphenyl diethyl phosphate
2,6-dimethylaniline
Conditions | Yield |
---|---|
With potassium; potassium amide In diethyl ether; ammonia at -78℃; 1.0-1.2 h; | 95% |
1、RTECS#: CAS# 87-62-7: ZE9275000
2、LD50/LC50: RTECS: CAS# 87-62-7: Oral, mouse: LD50 = 707 mg/kg;Oral, rat: LD50 = 840 mg/kg;.
3、Carcinogenicity: 2,6-Dimethylaniline - California: carcinogen, initial date 1/1/91 IARC: Group 2B carcinogen
4、Other: See actual entry in RTECS for complete information.
(1):Fire Fighting Measures of 2,6-Dimethylaniline
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Containers may explode in the heat of a fire. Combustible liquid.
Extinguishing Media: Use water spray to cool fire-exposed containers. Use water spray, dry chemical, carbon dioxide, or chemical foam.
(2):Accidental Release Measures of 2,6-Dimethylaniline
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Do not let this chemical enter the environment