- 2-Butanol
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- 2-Butanol, 3-methyl-,(2S)-
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Cas Database |
| Name |
2-Butanol |
EINECS | N/A |
| CAS No. | 15892-23-6 | Density | 0.808 g/mL at 25oC(lit.) |
| PSA | 20.23000 | LogP | 0.77720 |
| Solubility | N/A | Melting Point |
-115oC(lit.) |
| Formula | C4H10O | Boiling Point | 98oC(lit.) |
| Molecular Weight | 74.12160 | Flash Point | 80 °F |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | R10; R36/37 | |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Sec-butyl alcohol;S-sec-Butyl 3-methyl-2-butenethioate;3-Methylthiocrotonic acid,S-sec-butyl ester;sec-Butyl 3-methyl-2-butenethioate;2-Butanol, (±)-;1-methyl-1-propanol;sec-Butyl S-senecthioate; |
Article Data | 390 |
2-Butanol Chemical Properties
Chemistry informtion about 2-Butanol (CAS NO.15892-23-6) is:
IUPAC Name: butan-2-ol ; (2S)-butan-2-ol ; (2R)-butan-2-ol
Synonyms: Methylethylcarbinol ; Butan-2-Ol ; Butylene Hydrate ; Ethylmethylcarbinol ; 2-Butyl Alcohol ; 2-Hydroxybutane ; Secondary Butyl Alcohol ; S-Butyl Alcohol
MF: C4H10O
MW: 74.12
EINECS: 201-158-5
Melting Point: −115 °C(lit.)
Density: 0.801 g/cm3
Flash Point: 26.7 °C
Boiling Point: 96.6 °C at 760 mmHg
Vapour Pressure: 25.2 mmHg at 25°C
Enthalpy of Vaporization: 40.75 kJ/mol
Refractive Index: n20/D 1.397(lit.)
Following is the molecular structure of 2-Butanol (CAS NO.15892-23-6) is:
2-Butanol Uses
2-Butanol (CAS NO.15892-23-6) is used as a solvent, it is mainly converted to butanone ("MEK"), which is an important industrial solvent and found in many domestic cleaning agents and paint removers. Volatile esters of 2-butanol have pleasant aromas and are used in small amounts as perfumes or in artificial flavors.
2-Butanol Production
Raw materials: 1,3-Butadiene --> N-Butane --> Petroleum Ether --> Sec-Butanol --> Di-N-Butyl Sulfate --> Cis-2-Butene --> 2-Butene
2-Butanol Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| dog | LDLo | oral | 2400mg/kg (2400mg/kg) | National Technical Information Service. Vol. OTS0572377, | |
| frog | LDLo | parenteral | 15gm/kg (15000mg/kg) | Peripheral nerve and sensation: spastic paralysis with or without sensory change behavioral: somnolence (general depressed activity) | Archives Internationales de Pharmacodynamie et de Therapie. Vol. 50, Pg. 296, 1935. |
| guinea pig | LD50 | intraperitoneal | 1067mg/kg (1067mg/kg) | EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985. | |
| hamster | LD50 | intraperitoneal | 1218mg/kg (1218mg/kg) | EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985. | |
| mouse | LD50 | intraperitoneal | 771mg/kg (771mg/kg) | Shell Chemical Company. Unpublished Report. Vol. -, Pg. 2, 1961. | |
| mouse | LD50 | intravenous | 764mg/kg (764mg/kg) | Archives Internationales de Pharmacodynamie et de Therapie. Vol. 135, Pg. 330, 1962. | |
| rabbit | LD50 | intraperitoneal | 277mg/kg (277mg/kg) | EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985. | |
| rabbit | LD50 | oral | 4893mg/kg (4893mg/kg) | Sense organs and special senses: corneal damage: eye lungs, thorax, or respiration: dyspnea cardiac: pulse rate | Industrial Medicine and Surgery. Vol. 41, Pg. 31, 1972. |
| rat | LCLo | inhalation | 16000ppm/4H (16000ppm) | Sense organs and special senses: other changes: olfaction behavioral: somnolence (general depressed activity) lungs, thorax, or respiration: other changes | Shell Chemical Company. Vol. MSDS-5280-4, |
| rat | LD50 | intraperitoneal | 1193mg/kg (1193mg/kg) | EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985. | |
| rat | LD50 | intravenous | 138mg/kg (138mg/kg) | EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985. | |
| rat | LD50 | oral | 2193mg/kg (2193mg/kg) | Behavioral: somnolence (general depressed activity) behavioral: ataxia behavioral: coma | National Technical Information Service. Vol. OTS0557575, |
| rat | LD50 | skin | > 2gm/kg (2000mg/kg) | National Technical Information Service. Vol. OTS0557575, |
2-Butanol Safety Profile
Hazard Codes:
Xi: Irritant
Risk Statements:
R10:Flammable.
R36/37:Irritating to eyes and respiratory system.
R67:Vapours may cause drowsiness and dizziness.
Safety Statements:
S13:Keep away from food, drink and animal foodstuffs.
S24/25:Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S46:If swallowed, seek medical advice immediately and show this container or label.
S7/9:Keep container tightly closed and in a well-ventilated place.
RIDADR: UN 1120 3/PG 3
WGK Germany: 1
RTECS: EO1750000
2-Butanol Specification
2-Butanol (CAS NO.15892-23-6) is a flammable, colorless liquid that is soluble in 12 parts water and completely miscible with polar organic solvent such as ethers and other alcohols. It is produced on a large scale, primarily as a precursor to the industrial solvent methyl ethyl ketone.It is chiral and thus can be obtained as either of two stereoisomers designated as (R)-(−)-2-butanol and (S)-(+)-2-butanol. It is normally found as an equal mixture of the two stereoisomers — a racemic mixture.
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