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Cas Database |
| Name |
2-Ethylthiomethylphenyl N-methylcarbamate |
EINECS | 249-981-9 |
| CAS No. | 29973-13-5 | Density | 1.131g/cm3 |
| PSA | 63.63000 | LogP | 3.04880 |
| Solubility | 1800 mg l-1 (20 °C) | Melting Point |
33.4oC |
| Formula | C11H15 N O2 S | Boiling Point | 327.3°Cat760mmHg |
| Molecular Weight | 225.312 | Flash Point | 151.7°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Poison by ingestion and inhalation routes. Moderately toxic by skin contact. An insecticide. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also CARBAMATES. | Risk Codes | 22-50/53 |
| Molecular Structure |
|
Hazard Symbols |
 
|
| Synonyms |
Carbamicacid, methyl-, a-(ethylthio)-o-tolylester (8CI);Phenol, 2-[(ethylthio)methyl]-, methylcarbamate (9CI);o-Cresol, a-(ethylthio)-, methylcarbamate(8CI);2-[(Ethylthio)methyl]phenyl methylcarbamate;Arylmate;BAY-HOX 1901;Chox 1901;Croneton;Croneton 500;Ethiofencarb;HOX 1901;a-(Ethylthio)-o-tolylmethylcarbamate; |
Article Data | 3 |
2-Ethylthiomethylphenyl N-methylcarbamate Chemical Properties
Molecular Formula: C11H15NO2S
Molar mass: 225.3073 g/mol
EINECS: 249-981-9
Density: 1.131 g/cm3
Flash Point: 151.7 °C
Index of Refraction: 1.549
Storage temp: Approx 4 °C
Appearance: Red-brown oily liquid
Boiling Point: 327.3 °C at 760 mmHg
Vapour Pressure: 0.000204 mmHg at 25 °C
Solubility: Room temperature, the solubility of Benzene ,Toluene , Xylene , n-Propano l, Dichloromethane > 600g / L; water solubility of 900mg / L (1820mg / L)
Product categories of 2-Ethylthiomethylphenyl N-methylcarbamate (CAS NO.29973-13-5): Carbamates Alphabetic;Alpha sort;Carbamates Pesticides & Metabolites;Insecticides
Structure of 2-Ethylthiomethylphenyl N-methylcarbamate (CAS NO.29973-13-5):
XLogP3-AA: 1.9
H-Bond Donor: 1
H-Bond Acceptor: 2
IUPAC Name: [2-(Ethylsulfanylmethyl)phenyl] N-methylcarbamate
Canonical SMILES: CCSCC1=CC=CC=C1OC(=O)NC
InChI: InChI=1S/C11H15NO2S/c1-3-15-8-9-6-4-5-7-10(9)14-11(13)12-2/h4-7H,3,8H2,1-2H3,(H,12,13)
InChIKey: HEZNVIYQEUHLNI-UHFFFAOYSA-N
2-Ethylthiomethylphenyl N-methylcarbamate Uses
2-Ethylthiomethylphenyl N-methylcarbamate (CAS NO.29973-13-5) is an effective and low toxic residue carbamate insecticide within absorbent. It has a good control effect for the prevention for aphids, beetles, vegetable moths, cockroaches, mosquitoes, etc. andcould control of each of aphids on fruit trees, vegetables, potatoes, beet, tobacco and other crops. It is more effective for organophosphate resistant aphids with a long residual period of limitations.
2-Ethylthiomethylphenyl N-methylcarbamate Production
With phenol as raw materials, using step-pressure synthesis to get the intermediate o-Ethylthio-methyl phenol , then with Methyl isocyanate to obtain 2-Ethylthiomethylphenyl N-methylcarbamate (CAS NO.29973-13-5) .
2-Ethylthiomethylphenyl N-methylcarbamate Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| bird - domestic | LD50 | oral | 100mg/kg (100mg/kg) | Pesticide Manual. Vol. 9, Pg. 343, 1991. | |
| cat | LCLo | inhalation | 97mg/m3 (97mg/m3) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(10), Pg. 23, 1984. | |
| chicken | LD50 | oral | 1gm/kg (1000mg/kg) | Pesticide Manual. Vol. 9, Pg. 343, 1991. | |
| dog | LD50 | oral | 50mg/kg (50mg/kg) | Pesticide Manual. Vol. 9, Pg. 343, 1991. | |
| gerbil | LD50 | oral | 113mg/kg (113mg/kg) | Pesticide Biochemistry and Physiology. Vol. 21, Pg. 199, 1984. | |
| guinea pig | LD50 | oral | 113mg/kg (113mg/kg) | Pesticide Biochemistry and Physiology. Vol. 21, Pg. 199, 1984. | |
| man | TDLo | oral | 7143uL/kg (7.143mL/kg) | SENSE ORGANS AND SPECIAL SENSES: MIOSIS (PUPILLARY CONSTRICTION): EYE BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD LUNGS, THORAX, OR RESPIRATION: DYSPNEA | Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 37, Pg. 2029, 1995. |
| mouse | LD50 | oral | 71mg/kg (71mg/kg) | "Carbamate Insecticides: Chemistry, Biochemistry, and Toxicology," Kuhr, R.J., and H.W. Dorough, Cleveland, OH, CRC Press, 1976Vol. -, Pg. 106, 1976. | |
| mouse | LD50 | unreported | 63mg/kg (63mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(10), Pg. 23, 1984. | |
| quail | LD50 | oral | 155mg/kg (155mg/kg) | Pesticide Manual. Vol. 9, Pg. 343, 1991. | |
| rabbit | LD50 | skin | 2500mg/kg (2500mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(10), Pg. 23, 1984. | |
| rabbit | LD50 | unreported | 118mg/kg (118mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(10), Pg. 23, 1984. | |
| rat | LCLo | inhalation | 97mg/m3 (97mg/m3) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(10), Pg. 23, 1984. | |
| rat | LD50 | oral | 200mg/kg (200mg/kg) | Farm Chemicals Handbook. Vol. -, Pg. C85, 1991. | |
| rat | LD50 | skin | > 1150mg/kg (1150mg/kg) | Pesticide Manual. Vol. 9, Pg. 343, 1991. | |
| rat | LD50 | unreported | 400mg/kg (400mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(10), Pg. 23, 1984. |
2-Ethylthiomethylphenyl N-methylcarbamate Safety Profile
Poison by ingestion and inhalation routes. Moderately toxic by skin contact. An insecticide. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also CARBAMATES.
Hazard Codes: 
Xn,
N
Risk Statements: 22-50/53
R22:Harmful if swallowed.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 60-61
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
2-Ethylthiomethylphenyl N-methylcarbamate Specification
2-Ethylthiomethylphenyl N-methylcarbamate ,its cas register number is 29973-13-5. It also can be called Ethiofencarb ; 2-[(Ethylsulfanyl)methyl]phenyl-methylcarbamat ; a-Ethylthio-o-tolyl Methylcarbamate ; Dalf dust ; Boruho 50 and Croneton .
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