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| CAS No.: | 6976-93-8 |
|---|---|
| Name: | 2-Methoxyethyl methacrylate |
| Molecular Structure: | |
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| Formula: | C7H12O3 |
| Molecular Weight: | 144.17 |
| Synonyms: | Methacrylic acid,2-methoxyethyl ester (7CI,8CI);Ethanol, 2-methoxy-, methacrylate (8CI);2-Methoxyethyl methacrylate;Acryester MT;Acryics C 1;Blemmer PME 50;Methoxyethyl methacrylate;NSC 24157;b-Methoxyethyl methacrylate; |
| EINECS: | 230-241-9 |
| Density: | 0.993 |
| Boiling Point: | 65 °C12 mm Hg(lit.) |
| Flash Point: | 66 ºC |
| Solubility: | 31.33g/L at 20℃ |
| Hazard Symbols: |
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| Risk Codes: | R36/37/38;R43 |
| Safety: | 26-36 |
| PSA: | 35.53000 |
| LogP: | 0.75210 |
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- 6976-93-8
2-methoxyethyl (meth)acrylate
| Conditions | Yield |
|---|---|
| at 450℃; | |
| at 450℃; |
| Conditions | Yield |
|---|---|
| at 60℃; |
| Conditions | Yield |
|---|---|
| With sulfuric acid; benzene | |
| With sulfuric acid; benzene |
| Conditions | Yield |
|---|---|
| With triethylamine In benzene at 20℃; |
- 6976-93-8
2-methoxyethyl (meth)acrylate
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 2: 450 °C View Scheme | |
| Multi-step reaction with 2 steps 2: 450 °C View Scheme |
- 292638-84-7
styrene
- 6976-93-8
2-methoxyethyl (meth)acrylate
| Conditions | Yield |
|---|---|
| Stage #1: styrene With sec.-butyllithium In tetrahydrofuran; n-heptane at -78℃; for 0.333333h; Stage #2: 2-methoxyethyl (meth)acrylate With 1,1-Diphenylethylene; diethylzinc In tetrahydrofuran; n-heptane at -78℃; for 3h; | 100% |
- 6976-93-8
2-methoxyethyl (meth)acrylate
- polymer, Mn 37000 by end-group analysis using 1H NMR, Mw/Mn 1.16 by SEC, triad tacticity mm 3 percent, mr 32 percent, rr 65 percent by 1H NMR; monomer(s): 2-methoxyethyl methacrylate
polymer, Mn 37000 by end-group analysis using 1H NMR, Mw/Mn 1.16 by SEC, triad tacticity mm 3 percent, mr 32 percent, rr 65 percent by 1H NMR; monomer(s): 2-methoxyethyl methacrylate
| Conditions | Yield |
|---|---|
| With 1,1-Diphenylethylene; sec.-butyllithium In tetrahydrofuran; n-heptane at -78℃; for 2h; | 100% |
- 6976-93-8
2-methoxyethyl (meth)acrylate
- polymer, Mn 16000 by end-group analysis using 1H NMR, Mw/Mn 1.03 by SEC, triad tacticity mm 4 percent, mr 30 percent, rr 66 percent by 1H NMR; monomer(s): 2-methoxyethyl methacrylate
polymer, Mn 16000 by end-group analysis using 1H NMR, Mw/Mn 1.03 by SEC, triad tacticity mm 4 percent, mr 30 percent, rr 66 percent by 1H NMR; monomer(s): 2-methoxyethyl methacrylate
| Conditions | Yield |
|---|---|
| With 1,1-Diphenylethylene; sec.-butyllithium; lithium chloride In tetrahydrofuran; n-heptane at -78℃; for 2h; | 100% |
- 6976-93-8
2-methoxyethyl (meth)acrylate
- polymer, Mn 12000 by end-group analysis using 1H NMR, Mw/Mn 1.28 by SEC, triad tacticity mm 17 percent, mr 52 percent, rr 31 percent by 1H NMR; monomer(s): 2-methoxyethyl methacrylate
polymer, Mn 12000 by end-group analysis using 1H NMR, Mw/Mn 1.28 by SEC, triad tacticity mm 17 percent, mr 52 percent, rr 31 percent by 1H NMR; monomer(s): 2-methoxyethyl methacrylate
| Conditions | Yield |
|---|---|
| With (diphenylmethyl)potassium In tetrahydrofuran at -78℃; for 2h; | 100% |
- 6976-93-8
2-methoxyethyl (meth)acrylate
- polymer, Mn 14000 by end-group analysis using 1H NMR, Mw/Mn 1.04 by SEC, triad tacticity mm 13 percent, mr 52 percent, rr 35 percent by 1H NMR; monomer(s): 2-methoxyethyl methacrylate
polymer, Mn 14000 by end-group analysis using 1H NMR, Mw/Mn 1.04 by SEC, triad tacticity mm 13 percent, mr 52 percent, rr 35 percent by 1H NMR; monomer(s): 2-methoxyethyl methacrylate
| Conditions | Yield |
|---|---|
| With diethylzinc; (diphenylmethyl)potassium In tetrahydrofuran at -78℃; for 2h; | 100% |
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Specification
The 2-Methoxyethyl methacrylate, with the cas registry number 6976-93-8, has the systematic name of 2-methoxyethyl 2-methylprop-2-enoate. The molecular formula of the chemical is C7H12O3.
The characteristics of this chemical are as followings: (1)ACD/LogP: 1.04; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.04; (4)ACD/LogD (pH 7.4): 1.04; (5)ACD/BCF (pH 5.5): 3.65; (6)ACD/BCF (pH 7.4): 3.65; (7)ACD/KOC (pH 5.5): 87.9; (8)ACD/KOC (pH 7.4): 87.9; (9)#H bond acceptors: 3; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 5; (12)Polar Surface Area: 35.53 Å2; (13)Index of Refraction: 1.418; (14)Molar Refractivity: 37.56 cm3; (15)Molar Volume: 148.8 cm3; (16)Polarizability: 14.89×10-24cm3; (17)Surface Tension: 27.3 dyne/cm; (18)Density: 0.968 g/cm3; (19)Flash Point: 62.5 °C; (20)Enthalpy of Vaporization: 41.06 kJ/mol; (21)Boiling Point: 174.3 °C at 760 mmHg; (22)Vapour Pressure: 1.22 mmHg at 25°C.
You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin, and may cause sensitization by skin contact. Therefore, you had better take the following instructions: Wear suitable protective clothing, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.
Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: O=C(OCCOC)\C(=C)C
(2)InChI: InChI=1/C7H12O3/c1-6(2)7(8)10-5-4-9-3/h1,4-5H2,2-3H3
(3)InChIKey: YXYJVFYWCLAXHO-UHFFFAOYAE