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3-Bromoisobutyric acid

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Name

3-Bromoisobutyric acid

EINECS N/A
CAS No. 56970-78-6 Density 1.625g/cm3
PSA 37.30000 LogP 1.10200
Solubility N/A Melting Point 173 °C (decomp)
Formula C4H7 Br O2 Boiling Point 230.5°Cat760mmHg
Molecular Weight 167.002 Flash Point 93.2°C
Transport Information N/A Appearance N/A
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 56970-78-6 (3-BROMO-2-METHYLPROPIONIC ACID) Hazard Symbols N/A
Synonyms

Propionicacid, 3-bromo-2-methyl- (6CI,7CI); (?à)-3-Bromo-2-methylpropionic acid;3-Bromo-2-methylpropionic acid; NSC 201472; b-Bromoisobutanoic acid

Article Data 12

3-Bromoisobutyric acid Synthetic route

79-41-4

poly(methacrylic acid)

56970-78-6

3-bromo-2-methylpropionic acid

Conditions
ConditionsYield
With bromine; acetic acid91%
With hydrogen bromide In water at 60 - 65℃; Inert atmosphere;87.2%
With hydrogen bromide at 20℃; for 2h;70%
20609-71-6

3-bromo-2-methyl-propionic acid methyl ester

56970-78-6

3-bromo-2-methylpropionic acid

Conditions
ConditionsYield
With bis(tri-n-butyltin)oxide In toluene at 111℃; for 48h;60%
56970-78-6

3-bromo-2-methylpropionic acid

26473-47-2

2-methyl-3-sulfanylpropanoic acid

Conditions
ConditionsYield
With copper(l) iodide; sodium hydrogensulfide; tetrabutylammomium bromide In water at 65 - 75℃; Reagent/catalyst; Solvent; Inert atmosphere;92.6%
With sodium sulfide; water; sodium carbonate
56970-78-6

3-bromo-2-methylpropionic acid

654-70-6

4-amino-2-trifluoromethylbenzonitrile

3-bromo-N-(4-cyano-3-(trifluoromethyl)phenyl)-2-methylpropanamide

Conditions
ConditionsYield
With thionyl chloride; trimethylamine91%
Stage #1: 3-bromo-2-methylpropionic acid With thionyl chloride In tetrahydrofuran for 2h; Inert atmosphere;
Stage #2: 4-amino-2-trifluoromethylbenzonitrile With triethylamine In tetrahydrofuran at 50℃; for 2h; Inert atmosphere;
67-56-1

methanol

56970-78-6

3-bromo-2-methylpropionic acid

20609-71-6

3-bromo-2-methyl-propionic acid methyl ester

Conditions
ConditionsYield
With sulfuric acid90%
56970-78-6

3-bromo-2-methylpropionic acid

71271-28-8

3-bromo-2-methylpropanoyl chloride

Conditions
ConditionsYield
With thionyl chloride for 4h; Heating;77%
With thionyl chloride
With thionyl chloride
56970-78-6

3-bromo-2-methylpropionic acid

381-80-6

3-bromo-1,1,1-trifluoro-2-methylpropane

Conditions
ConditionsYield
With sulfur tetrafluoride; water for 24h; Autoclave;60%
56970-78-6

3-bromo-2-methylpropionic acid

1823-54-7

α-methyl-β-propiolactone

Conditions
ConditionsYield
With sodium hydroxide In chloroform for 2h; Cyclization;42%
108-02-1

captamine

56970-78-6

3-bromo-2-methylpropionic acid

α-methyl carboxybetaine disulfide

Conditions
ConditionsYield
Stage #1: 3-bromo-2-methylpropionic acid With sodium carbonate In ethanol; water at 1℃; for 20h;
Stage #2: captamine In ethanol at 40℃; for 72h; Inert atmosphere;
26%
56970-78-6

3-bromo-2-methylpropionic acid

<(32)S>-2-methyl-3-mercaptopropanoic acid

Conditions
ConditionsYield
With sodium hydroxide; (32)S-hydrogen sulfide at 95℃; for 3h;14%

3-Bromoisobutyric acid Chemical Properties

Molecular Structure:

Molecular Formula: C4H7BrO2
Molecular Weight: 167.0012
IUPAC Name: 3-Bromo-2-methylpropanoic acid
Synonyms of 3-Bromoisobutyric acid (CAS NO.56970-78-6): 3-Bromo-2-methylpropionic acid ; 2-Methyl-3-bromopropionic acid ; Methyl-3-bromopropionicacid ; 3-Bromo-2-methyl-propanoic acid
CAS NO: 56970-78-6 
Index of Refraction: 1.492
Molar Refractivity: 29.83 cm3
Molar Volume: 102.7 cm3
Surface Tension: 42.6 dyne/cm
Density: 1.625 g/cm3
Flash Point: 93.2 °C
Enthalpy of Vaporization: 51.45 kJ/mol
Boiling Point: 230.5 °C at 760 mmHg
Vapour Pressure of 3-Bromoisobutyric acid (CAS NO.56970-78-6): 0.0233 mmHg at 25°C

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