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| Name |
Allethrin |
EINECS | 209-542-4 |
| CAS No. | 584-79-2 | Density | 1.05 g/cm3 |
| PSA | 43.37000 | LogP | 4.00200 |
| Solubility | 2 mg l-1 | Melting Point |
51oC |
| Formula | C19H26O3 | Boiling Point | 386.8 °C at 760 mmHg |
| Molecular Weight | 302.414 | Flash Point | 166 °C |
| Transport Information | UN 3082 | Appearance | clear amber-colored viscous liquid |
| Safety | 36-60-61-36/37-24/25-23 | Risk Codes | 20/22-50/53-40 |
| Molecular Structure |
|
Hazard Symbols |
 Xn, N
|
| Synonyms |
Chrysanthemummonocarboxylicacid, 3-allyl-2-methyl-4-oxo-2-cyclopenten-1-yl ester (6CI);Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-,2-methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl ester (9CI);2-Cyclopenten-1-one,2-allyl-4-hydroxy-3-methyl-,2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate (8CI);2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid, ester with2-allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one;2-Allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one ester of 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid;3-(2-Propenyl)-2-methyl-4-oxo-2-cyclopentenyl3,3-dimethyl-2-(2-methyl-1-propenyl)cyclopropanecarboxylate;Allethrine;Allyl cinerin I;Bioallethrin;Depallethrine;EBT;ENT 17510;Esbiothrine;Matox;NSC 11782;OMS 3045;Pynamin forte;Pyresyn;RU 27436;Wasp Stopper CF;dl,d-T80 allethrin;trans-Allethrin; |
Allethrin Chemical Properties
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IUPAC Name: (2-Methyl-4-oxo-3-prop-2-enylcyclopent-2-en-1-yl)2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate
Empirical Formula: C19H26O3
Molecular Weight: 302.4079
Index of Refraction: 1.515
Molar Refractivity: 86.75 cm3
Molar Volume: 287.5 cm3
Surface Tension: 36.3 dyne/cm
Density: 1.05 g/cm3
Flash Point: 166 °C
Enthalpy of Vaporization: 63.57 kJ/mol
Boiling Point: 386.8 °C at 760 mmHg
Vapour Pressure: 3.46E-06 mmHg at 25 °C
EINECS: 209-542-4
Classification Code of Allethrin (CAS NO.584-79-2): Agricultural Chemical; Insecticide; Insecticides; Mutation data; Pesticides
Allethrin Uses
Allethrin (CAS NO.584-79-2) is used in many household insecticides such as RAID as well as mosquito coils. Insects subject to its exposure become paralyzed before dying. They are also used as an ultra low volume spray for outdoor mosquito control.
Allethrin Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LC50 | inhalation | > 2gm/m3 (2000mg/m3) | Yakkyoku. Pharmacy. Vol. 37, Pg. 187, 1986. | |
| mouse | LD50 | intraperitoneal | 38mg/kg (38mg/kg) | Journal of Agricultural and Food Chemistry. Vol. 31, Pg. 250, 1983. | |
| mouse | LD50 | oral | 370mg/kg (370mg/kg) | Agricultural and Biological Chemistry. Vol. 28, Pg. 914, 1965. | |
| mouse | LD50 | skin | 1200mg/kg (1200mg/kg) | Agricultural and Biological Chemistry. Vol. 27, Pg. 684, 1963. | |
| mouse | LDLo | intracrebral | 4mg/kg (4mg/kg) | Toxicology and Applied Pharmacology. Vol. 66, Pg. 290, 1982. | |
| quail | LD50 | oral | 2030mg/kg (2030mg/kg) | Pesticide Manual. Vol. 9, Pg. 19, 1991. | |
| rabbit | LD50 | intraperitoneal | 11200mg/kg (11200mg/kg) | World Review of Pest Control. Vol. 3, Pg. 28, 1964. | |
| rabbit | LD50 | oral | 4290mg/kg (4290mg/kg) | Special Publication of the Entomological Society of America. Vol. 78-1, Pg. 7, 1978. | |
| rabbit | LD50 | skin | 11332mg/kg (11332mg/kg) | BEHAVIORAL: TREMOR BEHAVIORAL: EXCITEMENT | AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 2, Pg. 420, 1950. |
| rat | LCLo | inhalation | 13800mg/m3/4H (13800mg/m3) | BEHAVIORAL: TREMOR BEHAVIORAL: EXCITEMENT | AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 2, Pg. 420, 1950. |
| rat | LD50 | oral | 685mg/kg (685mg/kg) | Farm Chemicals Handbook. Vol. -, Pg. C255, 1991. | |
| rat | LD50 | skin | 2500mg/kg (2500mg/kg) | Yakkyoku. Pharmacy. Vol. 37, Pg. 187, 1986. | |
| rat | LD50 | unreported | 680mg/kg (680mg/kg) | "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 131, 1971. | |
| rat | LDLo | intravenous | 4mg/kg (4mg/kg) | BEHAVIORAL: TREMOR BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: AGGRESSION | Pesticide Biochemistry and Physiology. Vol. 2, Pg. 308, 1972. |
Allethrin Safety Profile
Hazard Codes:
Xn,
N
Risk Statements: 20/22-50/53
R20/22:Harmful by inhalation and if swallowed.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 36-60-61
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S36:Wear suitable protective clothing.
RIDADR: UN 3352
Allethrin Specification
Allethrin (CAS NO.584-79-2), its Synonyms are (+)-Allelrethonyl (+)-cis,trans-chrysanthemate ; (+)-trans-Chrysanthemumic acid ester of (+-)-allethrolone ; (RS)-3-Allyl-2-methyl-4-oxocyclopent-2-enyl (+-)-cis,trans-chrysanthemate ; 3-Allyl-2-methyl-4-oxo-2-cyclopenten-1-yl chrysanthemate ; Allethrolone ester of chrysanthemummonocarboxylic acid ; Cinerin I allyl homolog .
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