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Allyltriphenyltin

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Name

Allyltriphenyltin

EINECS N/A
CAS No. 76-63-1 Density 1,07 g/cm3
PSA 0.00000 LogP 3.34280
Solubility Insoluble in water Melting Point 71-74 °C(lit.)

Formula C21H20 Sn Boiling Point 421.4°C at 760 mmHg
Molecular Weight 391.1 Flash Point >100
Transport Information N/A Appearance N/A
Safety Poison by intravenous route. See also TIN COMPOUNDS and ALLYL COMPOUNDS. When heated to decomposition it emits toxic smoke and irritating fumes.

Analytical Methods:

   

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

Risk Codes R23/24/25; R50/53
Molecular Structure Molecular Structure of 76-63-1 (ALLYLTRIPHENYLTIN) Hazard Symbols A poison. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
Synonyms

Stannane,allyltriphenyl- (8CI); Stannane, triphenyl-2-propenyl- (9CI); Tin,allyltriphenyl- (6CI,7CI); 3-(Triphenylstannyl)-1-propene;Allyltriphenylstannane; Allyltriphenyltin; Dowco 187; ENT 50909; NSC 227360;NSC 99168; Triphenyl(2-propenyl)stannane

Article Data 20

Allyltriphenyltin Chemical Properties

Molecular Structure of Allyltriphenyltin (CAS NO.76-63-1):


IUPAC: Triphenyl(prop-2-en-1-yl)stannane
Molecular Weight: C21H20Sn
Molecular Weight: 391.09
EINECS: 200-975-4
Product Categories: Classes of Metal Compounds;Sn (Tin) Compounds;Typical Metal Compounds
Melting point: 71-74oC(lit.)
density: 1.07 g/cm3
Boiling point: 421.4oC at 760 mmHg
Flash point: 211.8oC
Enthalpy of Vaporization: 64.92 kJ/mol
Vapour Pressure: 6.42E-07 mmHg at 25oC
SMILES: C(=C)\C[Sn](c1ccccc1)(c2ccccc2)c3ccccc3
InChI: InChI=1/3C6H5.C3H5.Sn/c3*1-2-4-6-5-3-1;1-3-2;/h3*1-5H;3H,1-2H2;/rC21H20Sn/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h2-17H,1,18H2
InChIKey: NDUYAGLANMHJHF-RLXLSUHDAH 

Allyltriphenyltin Toxicity Data With Reference

1.    

ivn-mus LD50:100 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#02200 .

Allyltriphenyltin Safety Profile

Poison by intravenous route. See also TIN COMPOUNDS and ALLYL COMPOUNDS. When heated to decomposition it emits toxic smoke and irritating fumes.    

Safety Information of Allyltriphenyltin (CAS NO.76-63-1):
Hazard Codes:TToxic,NDangerous
Risk Statements:23/24/25-50/53
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:26-27-28-45-60-61
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27:Take off immediately all contaminated clothing.
S28:After contact with skin, wash immediately with plenty of soap-suds.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR:UN 3146 6.1/PG 3
WGK Germany:3
RTECS:WH6705000
TSCA:No
HazardClass:6.1(b)
PackingGroup:III

Allyltriphenyltin Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3

Allyltriphenyltin Analytical Methods

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

Allyltriphenyltin Specification

 Allyltriphenyltin with cas registry number of 76-63-1 is also known as Allyltriphenylstannane ; Triphenyl-2-propenylstannane ; Allyltriphenylstannane ; Stannane, allyltriphenyl- ; Stannane, triphenyl-2-propenyl- (9CI) . Allyltriphenyltin with cas registry number of 76-63-1 is a typical metal compound which is used as a intermediate.

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