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Basic Orange 2

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Basic Orange 2

EINECS 208-545-8
CAS No. 532-82-1 Density 1.2171 (rough estimate)
PSA 76.76000 LogP 5.23080
Solubility N/A Melting Point 235 °C (dec.)(lit.)
Formula C12H13ClN4 Boiling Point 454 °C at 760 mmHg
Molecular Weight 248.715 Flash Point 228.4 °C
Transport Information UN 3077 9/PG 3 Appearance red-brown powder, large black shiny crystals with a green luster or purple powder
Safety 60-61 Risk Codes 50/53
Molecular Structure Molecular Structure of 532-82-1 (Basic Orange 2) Hazard Symbols DangerousN
Synonyms

1,3-Benzenediamine,4-(phenylazo)-, monohydrochloride (9CI);C.I. Basic Orange 2 (6CI);C.I. Basic Orange2, monohydrochloride (8CI);2,4-Diaminoazobenzene hydrochloride;AstraChrysoidine R;1,3-Benzenediamine,4-(2-phenyldiazenyl)-, hydrochloride (1:1);Brasilazina Orange Y;C.I. 11270;Chrysoidine;Chrysoidine A;Chrysoidine B;Chrysoidine C;Chrysoidine J;Chrysoidine PRR;Chrysoidine YN;Chrysoidine orange;Diazocard Chrysoidine G;Nippon Kagaku Chrysoidine;Sugai Chrysoidine;Tertrophene Brown CG;Verona Chrysoidine GN;

 

Basic Orange 2 Chemical Properties

The Molecular Structure of Basic Orange 2 (CAS NO.532-82-1):

IUPAC Name: 4-Phenyldiazenylbenzene-1,3-diamine hydrochloride 
Molecular Weight: 248.71142 g/mol
Molecular Formula: C12H13ClN4 
Melting Point: 235 °C (dec.)(lit.)
Flash Point: 228.4 °C
Enthalpy of Vaporization: 72.72 kJ/mol
Boiling Point: 454 °C at 760 mmHg
Vapour Pressure: 1.2E-08 mmHg at 25 °C
H-Bond Donor: 3
H-Bond Acceptor: 4
Rotatable Bond Count: 2
Tautomer Count: 12
Exact Mass: 248.082874
MonoIsotopic Mass: 248.082874
Topological Polar Surface Area: 76.8
Heavy Atom Count: 17
Canonical SMILES: C1=CC=C(C=C1)N=NC2=C(C=C(C=C2)N)N.Cl
InChI: InChI=1S/C12H12N4.ClH/c13-9-6-7-12(11(14)8-9)16-15-10-4-2-1-3-5-10;/h1-8H,13-14H2;1H
InChIKey: MCTQNEBFZMBRSQ-UHFFFAOYSA-N
EINECS: 208-545-8
Product Categories: Dyes and Pigments; Organics; Solvent Dyestuff

Basic Orange 2 Uses

 Basic Orange 2 (CAS NO.532-82-1) is used in dying of cotton, acrylic, leather, paper, feathers, leather, wood, bamboo, other products and silk.

Basic Orange 2 Toxicity Data With Reference

1.    

mma-sat 50 µg/plate

    MUREAV    Mutation Research. 44 (1977),9.
2.    

mmo-smc 100 µg/L

    VINIT*    Vsesoyuznyi Institut Nauchnoi i Tekhnicheskoi Informatsii (VINITI). All-Union Institute of Scientific and Technical Information. (Moscow, USSR) #428-84 .
3.    

orl-mus LDLo:1670 mg/kg

    AEPPAE    Naunyn-Schmiedeberg’s Archiv fuer Experimentelle Pathologie und Pharmakologie. 195 (1940),295.
4.    

scu-mus LDLo:1670 mg/kg

    AEPPAE    Naunyn-Schmiedeberg’s Archiv fuer Experimentelle Pathologie und Pharmakologie. 195 (1940),295.

Basic Orange 2 Consensus Reports

IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 169.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 8 ,1975,p. 91.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Basic Orange 2 Safety Profile

Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and HCl. Used as a colorant in textiles, paper, leather, inks, wood, and biological stains.
Hazard Codes: N
Risk Statements: 50/53
R50/53:  Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 
Safety Statements: 60-61
S60:  This material and/or its container must be disposed of as hazardous waste
S61:  Avoid release to the environment. Refer to special instructions safety data sheet  
RIDADR: UN 3077 9/PG 3
WGK Germany: 2
RTECS: ST3380000

Basic Orange 2 Specification

 Basic Orange 2 (CAS NO.532-82-1) is also named as 2,4-Diaminoazobenzene hydrochloride ; 4-(Phenylazo)-1,3-benzenediamine, monohydrochloride ; 4-(Phenylazo)-1,3-phenylenediamine, monohydrochloride ; 4-(Phenylazo)-m-phenylenediamine, monohydrochloride ; Astra Chrysoidine R ; Atlantic Chrysoidine Y ; Basonyl Orange 200 ; Brasilazina Orange Y ; Brilliant Oil Orange Y Base ; C.I. 11270 ; C.I. Basic Orange 2 ; C.I. Basic Orange 2, monohydrochloride ; C.I. Basic Orange 3 ; CCRIS 162 ; Chrysoidine Crystals ; Chrysoidine G ; Chrysoidine GN ; Chrysoidine GS ; Elcozine chrysoidine Y ; HSDB 5491 ; Leather Orange HR ; NSC 152834 ; Nippon Kagaku Chrysoidine ; Pure Chrysoidine YBH ; Pure chrysoidine YD ; Pyracryl Orange Y ; Sugai Chrysoidine ; Tertrophene Brown CG ; Verona Chrysoidine GN ; m-Phenylenediamine, 4-(phenylazo)-, hydrochloride ; m-Phenylenediamine, 4-(phenylazo)-, monohydrochloride . Basic Orange 2 (CAS NO.532-82-1) is red-brown powder, large black shiny crystals with a green luster or purple powder. It is slightly soluble in water. Basic Orange 2 is an azo compound. Azo dyes can be explosive when suspended in air at specific concentrations. Toxic gases are formed by mixing compounds containing azo groups with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. Basic Orange 2 is incompatible with strong oxidizing agents. Flash point data for Basic Orange 2 are not available. It is probably combustible.

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