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Bis(Trimethylsilyl)Carbodiimide

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Name

Bis(Trimethylsilyl)Carbodiimide

EINECS 213-673-2
CAS No. 1000-70-0 Density 0.821
PSA 24.72000 LogP 2.83010
Solubility N/A Melting Point -23 ºC
Formula C7H18 N2 Si2 Boiling Point 164 ºC
Molecular Weight 186.404 Flash Point 42 ºC
Transport Information UN 1993 Appearance clear colorless liquid
Safety Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NOx. Risk Codes R10;R22;R36/37/38   
Molecular Structure Molecular Structure of 1000-70-0 (Bis(trimethylsilyl)carbodiimide) Hazard Symbols
Synonyms

Carbodiimide,bis(trimethylsilyl)- (7CI,8CI); 1,3-Bis(trimethylsilyl)carbodiimide;Bis(trimethylsilyl)carbodiimide; N,N-Bis(trimethylsilyl)carbodiimide;N,N'-Bis(trimethylsilyl)carbodiimide;N,N'-Methanetetraylbis[1,1,1-trimethylsilylamine]

Article Data 32

Bis(Trimethylsilyl)Carbodiimide Chemical Properties

Chemistry informtion about Bis(Trimethylsilyl)Carbodiimide (CAS NO.1000-70-0) is:
IUPAC Name: N,N'-Bis(Trimethylsilyl)Methanediimine
Synonyms: Bis(Trimethylsilyl)-Carbodiimid ; N,N'-Methanetetraylbis(1,1,1-Trimethyl-Silanamin ; N,N'-Methanetetraylbis(1,1,1-Trimethylsilanamine) ; N,N'-Methanetetraylbis[1,1,1-Trimethyl-Silanamin ; 1,3-Bis(Trimethylsilyl)Carbodiimide ; Bis(Trimethylsilyl)Carbodiimide ; Btscd ; N,N'-Methanetetraylbis[1,1,1-Trimethylsilylamine]
Product Categories: Industrial/Fine Chemicals ; Si (Classes of Silicon Compounds) ; Si-N Compounds ; Trimethylsilylazide, etc. ; C-X Bond Formation (Non-Halogen) ; Others ; Synthetic Reagents
MF: C7H18N2Si2
MW: 186.4
EINECS: 213-673-2
Density: 0.81 g/cm3  
Melting Point: −23 °C(lit.)
Flash Point: 54.1 °C
Boiling Point: 165.8 °C at 760 mmHg
Vapour Pressure: 2.43 mmHg at 25°C
Enthalpy of Vaporization: 38.57 kJ/mol
Refractive Index: n20/D 1.434(lit.)
Storage temp.: Flammables area
Sensitive: Moisture Sensitive
BRN: 2042082
Following is the molecular structure of Bis(Trimethylsilyl)Carbodiimide (CAS NO.1000-70-0) is:

Bis(Trimethylsilyl)Carbodiimide Toxicity Data With Reference

1.    

orl-rat LD50:1728 mg/kg

    GISAAA    Gigiena i Sanitariya. 55 (6)(1990),86.
2.    

orl-rbt LD50:1728 mg/kg

    GISAAA    Gigiena i Sanitariya. 55 (6)(1990),86.

Bis(Trimethylsilyl)Carbodiimide Consensus Reports

Reported in EPA TSCA Inventory.

Bis(Trimethylsilyl)Carbodiimide Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NOx
Hazard Codes:
FlammableF
HarmfulXn
Risk Statements:
R11:Highly flammable. 
R22:Harmful if swallowed. 
R36/37/38:Irritating to eyes, respiratory system and skin. 
R10:Flammable.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing. 
S37/39:Wear suitable gloves and eye/face protection. 
S16:Keep away from sources of ignition.
RIDADR: UN 1993 3/PG 2
WGK Germany: 3
RTECS: VV1302500
F: 
F 10: Keep under argon.
F 21: Sensitive to humidity.
TSCA: Yes
HazardClass: 3
PackingGroup: III

Bis(Trimethylsilyl)Carbodiimide Specification

Bis(Trimethylsilyl)Carbodiimide (CAS NO.1000-70-0) is a clear colorless liquid.
First Aid Measures:
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.
Handling and Storage:
Handling: Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.

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