(R)- AND (S)-2-ACETOXY-1,1,2-TRIPHENYLETHANOL - EFFECTIVE SYNTHETIC EQUIVALENTS OF A CHIRAL ACETATE ENOLATE
The enolate 3, easily available by double deprotonation of (R)-2-acetoxy-1,1,2-triphenylethanol (5), adds in a highly stereoselective manner to aldehides.Hydrolysis of the adducts 6/7 affods the acids 2.
Braun, Manfred,Devant, Ralf
p. 5031 - 5034
(2007/10/02)
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