10212-03-0

Basic information

• Product Name: 3-Bromophenyl)diphenylphosphine
• Synonyms: 3-Bromophenyl)diphenylphosphine
• CAS NO: 10212-03-0
• Molecular Formula: C₁₈H₁₄BrP
• Molecular Weight: 372.43978
• Mol File: 10212-03-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Bromophenyl)diphenylphosphine(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Bromophenyl)diphenylphosphine(10212-03-0)
• EPA Substance Registry System: 3-Bromophenyl)diphenylphosphine(10212-03-0)

Safety Data

• Hazardous Substances Data: 10212-03-0(Hazardous Substances Data)

Usage

Uses

Used in Coordination Chemistry:
3-Bromophenyl)diphenylphosphine is used as a ligand in coordination chemistry for its ability to form stable complexes with transition metals. Its presence enhances the stability and reactivity of metal complexes, making it a valuable component in various chemical reactions.
Used in Organometallic Catalysis:
In organometallic catalysis, 3-Bromophenyl)diphenylphosphine is employed as a ligand to improve the efficiency and selectivity of catalytic reactions. Its electron-donating properties and steric effects contribute to the modulation of catalytic activity and selectivity.
Used in Transition Metal Complexes for Catalytic Reactions:
3-Bromophenyl)diphenylphosphine is used as a ligand in transition metal complexes for various catalytic reactions, such as coupling and hydrogenation reactions. Its unique structure allows it to facilitate these reactions by stabilizing intermediates and enhancing the catalytic activity of the metal center.
Used in Organic Synthesis:
3-Bromophenyl)diphenylphosphine is utilized in organic synthesis as a building block for more complex phosphine ligands. Its presence in these ligands can influence the outcome of organic reactions, providing a means to control reaction pathways and improve synthetic efficiency.
Used in the Development of New Phosphine Ligands:
3-Bromophenyl)diphenylphosphine is used as a starting material for the synthesis of new phosphine ligands with tailored properties. These ligands can be designed to meet specific requirements in various chemical processes, expanding the scope of applications in coordination chemistry and catalysis.

Upstream product

• 106-37-6 1.4-dibromobenzene 
• 1079-66-9 chloro-diphenylphosphine 
• 591-18-4 1-Bromo-3-iodobenzene 
• 1147860-64-7 H₃B(PPh₂(C₆H₄Br)) 
• 829-85-6 diphenylphosphane 
• 108-36-1 1,3-dibromobenzene 

Downstream Products

• 50777-69-0 3-(diphenylphosphanyl)benzaldehyde 
• 1376532-19-2 7-[3-(diphenylthiophosphoryl)phenyl]-3,4,5,6-tertrahydro-2H-azepine 
• 1416307-52-2 C₄₂H₃₃O₃P₃ 
• 1416307-51-1 C₄₂H₃₃P₃ 
• 10212-04-1 (3-bromophenyl)-diphenylphosphine oxide 
• 1376532-13-6 5-[3-(diphenylthiophosphoryl)phenyl]-3,4-dihydro-2H-pyrrole 
• 1346518-79-3 C₂₅H₂₀NOP 
• 1240453-70-6 [m-(HOMe₂CCC)C₆H₄]PPh₂ 
• 651329-73-6 (C₄H₈)2N⁽¹⁺⁾*(C₆H₅)2PC₆H₄B(C₆H₅)3^(1-)=((C₄H₈)2N)((C₆H₅)2PC₆H₄B(C₆H₅)3) 
• 328917-28-8 2-[3-(diphenylphosphanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxoborolane 
• 65754-17-8 N-tert-Butyl-N-[3-(diphenyl-phosphinothioyl)-phenyl]-hydroxylamine 
• 65754-15-6 N-tert-Butyl-N-[3-(diphenyl-phosphinoyl)-phenyl]-hydroxylamine 
• 328917-29-9 (3-(4,4,5,5-tetramethyl-1,3,2-dioxoborolan-2-yl)phenyl)diphenylphosphine oxide 

Relevant articles and documents

Highly efficient yellow phosphorescent organic light-emitting diodes with novel phosphine oxide-based bipolar host materials

Two bipolar host materials, (4-((4-(naphthalen-1-yl(phenyl)amino)naphthalen-1-yl)(phenyl)amino)phenyl)diphenylphosphine oxide (POpN) and (3-((4-(naphthalen-1-yl(phenyl)amino)naphthalen-1-yl)(phenyl)amino)phenyl)diphenylphosphine oxide (POmN), comprising a hole-transporting N1-(naphthalen-1-yl)-N1,N4-diphenylnaphthalene-1,4-diamine (NPNA2) donor and an electron-transporting phosphine oxide (PO) acceptor at different positions of the phenyl bridge have been synthesized. POpN (glass transition temperature Tg = 119 °C) and POmN (Tg = 115 °C) exhibit high morphological stability. Two yellow phosphorescent organic light-emitting diodes (PhOLEDs, ITO (indium tin oxide)/TAPC (1,1-bis[4-(di-p-tolylamino)phenyl]cyclohexane, 40 nm)/POpN or POmN: Ir(bt)2(acac) (bis(2-phenylbenzothiozolato-N,C2′)iridium(acetylacetonate), 15 wt%, 20 nm)/TmPyPB (1,3,5-tri(m-pyrid-3-yl-phenyl)benzene, 40 nm)/LiF (1 nm)/Al (100 nm)) exhibit maximum luminances (Lmax) of 82:057 and 78:385 cd m-2, maximum current efficiencies (ηc,max) of 68.28 and 44.95 cd A-1, respectively, with low efficiency roll-off.

Tetraarylphosphonium salts as solubility-control groups: Phosphonium-supported triphenylphosphine and azodicarboxylate reagents

(Chemical Equation Presented) Predictable solubilities! Reagents supported on a tetraarylphosphonium group have solubilities that can be predicted. The reagents and their by-products can be readily removed, recovered, and recycled after reaction by a precipitation/filtration sequence initiated by the addition of a low-polarity solvent, such as diethyl ether. Furthermore, the supported reagents are robust and exhibit reactivities similar to their parent compounds.

Triazinyl derivative organic electron transport material as well as preparation method and application thereof

The invention belongs to the technical field of organic photoelectric functional materials, and discloses a triazinyl derivative organic electron transport material as well as a preparation method andapplication thereof. The triazinyl derivative organic electron transport material is more than one material represented by a formula I or a formula II. The invention also discloses a preparation method of the triazinyl derivative organic electron transport material. The method disclosed by the invention is simple and easy to purify, the influence of a halogen intermediate on the stability of thedevice is easy to eliminate, and meanwhile, the material disclosed by the invention has good electron transport performance, high thermal stability and high glass-transition temperature; and meanwhile, the material has high stability in an OLED phosphorescent device. The organic electron transport material is used for preparing photoelectric devices such as organic electroluminescence devices andthe like.

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Phosphine oxide-based compound and organic light emitting device comprising the same

Phosphine oxide based compounds and is disclosure is an organic light emitting device. (by machine translation)

Condensed-cyclic compound and organic light emitting diode comprising the same

Disclosed are a condensed-cyclic compound, and an organic light emitting device comprising the same. The condensed-cyclic compound is represented by chemical formula 1. The organic light emitting device comprising the condensed-cyclic compound has low driving voltage, high efficiency, high luminance, and long lifespan.COPYRIGHT KIPO 2016

Organic molecule electron transmission material with high triplet level and preparing method and application thereof

The invention discloses an organic molecule electron transmission material with a high triplet level. Electrophilic n-heterocyclic and diphenylphosphine oxide are introduced at the same time, aryl or fused ring aryl is connected with functional groups at

Condensed-cyclic compound and organic light emitting device comprising the same

Disclosed are a condensed-ring compound and an organic light emitting device comprising the same. The condensed-ring compound is represented by the chemical formula 1-2 or 1-3. The organic light emitting device comprising the condensed-ring compound can have a low driving voltage, high efficiency, high brightness, and long lifespan.COPYRIGHT KIPO 2016

NOVEL COMPOUND AND ORGANIC DEVICE EMPLOYING SAME

The compounds represented by the following general formula have excellent properties as a charge transport material. In the formula, R1 to R3 represent a substituent, n1 and n2 indicate an integer of from 0 to 5, n3 indicates an inte