10215-30-2

Basic information

• Product Name: 1-Propanol, 2-propoxy-
• Synonyms: 1-Propanol, 2-propoxy-;2-Propoxy-1-Propanol
• CAS NO: 10215-30-2
• Molecular Formula: C₆H₁₄O₂
• Molecular Weight: 118.17
• Mol File: 10215-30-2.mol

Chemical Properties

• Boiling Point: 157.8°Cat760mmHg
• Flash Point: 50.2°C
• Appearance: /
• Density: 0.896g/cm³
• Vapor Pressure: 0.968mmHg at 25°C
• Refractive Index: 1.416
• PKA: 14.47±0.10(Predicted)
• CAS DataBase Reference: 1-Propanol, 2-propoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanol, 2-propoxy-(10215-30-2)
• EPA Substance Registry System: 1-Propanol, 2-propoxy-(10215-30-2)

Safety Data

• Hazardous Substances Data: 10215-30-2(Hazardous Substances Data)

Usage

Uses

Used in Chemical Industry:
1-Propanol, 2-propoxyis used as a solvent for various chemical processes, providing a medium for reactions to occur and facilitating the dissolution of other substances.
Used in Coatings Production:
In the coatings industry, 1-Propanol, 2-propoxyis used as a component in the formulation of coatings, contributing to their performance characteristics such as drying time, adhesion, and durability.
Used in Inks Production:
1-Propanol, 2-propoxyis utilized in the production of inks, where it helps to control the viscosity and flow properties of the ink, ensuring consistent application and print quality.
Used in Cleaning Products:
As a component in cleaning products, 1-Propanol, 2-propoxyaids in the dissolution of dirt, grease, and other contaminants, enhancing the cleaning efficacy of the product.
Used in Organic Synthesis:
1-Propanol, 2-propoxyserves as a synthetic intermediate in organic chemistry, enabling the synthesis of more complex molecules and compounds for various applications.

InChI:InChI=1/C6H14O2/c1-3-4-8-6(2)5-7/h6-7H,3-5H2,1-2H3

Upstream product

• 71-23-8 propan-1-ol 
• 75-56-9 methyloxirane 
• 57-55-6 propylene glycol 

Relevant articles and documents

Catalytic deoxygenation of 1,2-propanediol to give n-propanol

Deoxygenation of 1,2-propanediol (1.0M in sulfolane) catalyzed by bis(dicarbonyl)(μhydrido)(pentamethylcyclopentadiene)ruthenium trifluoromethanesulfonate ({[Cp*Ru(CO)2]2(μ.-H)} +OTf-) (0.5 mol%) at 110°C under hydrogen (750 psi) in the presence of trifluoromethanesulfonic acid (HOTf) (60 mM) gives n-propanol as the major product, indicating high selectivity for deoxygenation of the internal hydroxy group over the terminal hydroxy group of the diol. The deoxygenation of 1,2-propanediol is strongly influenced by the concentration of acid, giving faster rates and proceeding to higher conversions as the concentration of HOTf is increased. Propionaldehyde was observed as an intermediate, being formed through acid-catalyzed dehydration of 1,2-propanediol. This aldehyde is hydrogenated to n-propanol through an ionic pathway involving protonation of the aldehyde, followed by hydride transfer from the neutral hydride, dicarbonyl(pentamethylcyclopentadiene)ruthenium hydride [Cp*Ru(CO)2H]. The proposed mechanism for the deoxygenation/hydrogenation reaction involves formation of a highly acidic dihydrogen complex [Cp*Ru(CO)2(η2-H 2)]+ OTf-.

MBA-cross-linked poly(N-vinyl-2-pyrrolidone)/ferric chloride macromolecular coordination complex as a novel and recyclable Lewis acid catalyst: Synthesis, characterization, and performance toward for regioselective ring-opening alcoholysis of epoxides

A novel macromolecular-metal coordination complex, MBA-cross-linked PNVP/FeCl3 material was fabricated by immobilization of water intolerant ferric chloride onto the porous cross-linked poly(N-vinyl-2-pyrrolidone) carrier beads as a macromolecular ligand or carrier which was prepared by suspension free-radical copolymerization of N-vinyl-2-pyrrolidone (NVP) and N,N′-methylene bis-acrylamide (MBA) as a crosslinking agent in water. The obtained PNVP/FeCl3 was characterized by UV/vis and FT-IR spectroscopies, TGA, FE-SEM, EDX, and ICP techniques. This heterogenized version of ferric chloride is a convenient and safe alternative to highly water intolerant ferric chloride. The catalytic performance of (PNVP/FeCl3) as an efficient and recyclable polymeric Lewis acid catalyst was appropriately probed in the regio-and stereoselective nucleophilic ring opening of various epoxides with various alcohols in excellent yields with TOF up to 182.48 h?1 without generating any waste. The activity data indicate that this heterogeneous catalyst is very active and could be easily recovered, and reused at least six times without appreciable loss of activity indicating its stability under experimental conditions.

METHODS OF CONVERTING POLYOLS

Methods for converting polyols are provided. The methods provided can include using a metal pincer catalyst (e.g., an iridium pincer catalyst) to remove at least one alcohol group from a polyol. The methods provided can include converting glycerol to 1,3-propanediol.

Metal-catalyzed selective deoxygenation of diols to alcohols

The internal OH group of 1,2-propanediol is selectively removed in the deoxygenation catalyzed by [{Cp*Ru(CO)2}2(μ-H)]+OTf - (1, Cp=C3Me5, OTf=trifluoromethanesulfonate; see scheme). This reaction provides a model for deoxygenation of polyols derived from carbohydrates, for use in alternative, biomass-based feedstock applications. An ionic mechanism is proposed that involves the dihydrogen complex [Cp*Ru(CO)2(η2-H2)]+.

The Use of Proton-exchanged X-Type Zeolite in Catalysing Ring-opening Reactions of 2-Substituted Epoxides with Nucleophiles and its Effect on Regioselectivity

The use of proton-exchanged X-type zeolite in catalysing ring-opening reactions of 2-alkyl substituted epoxides with nucleophiles gives a high regioselectivity and functional-selective catalysis giving allylic products from allylic nucleophiles.Mechanistic aspects are discussed.