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N,N'-Di-(4-methyl-phenyl)-benzidine is a chemical compound that serves as an intermediate in the production of dyes, pigments, rubber, and plastics. It is recognized for its toxic and harmful effects on human health and the environment, being classified as a substance of very high concern by the European Chemicals Agency. Its exposure is associated with an increased risk of bladder cancer, necessitating strict regulations and control measures to mitigate its impact.

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  • 10311-61-2 Structure
  • Basic information

    1. Product Name: N,N'-Di-(4-methyl-phenyl)-benzidine
    2. Synonyms: N,N'-Di-(4-methyl-phenyl)-benzidine;N,N'-Bis(4-methylphenyl)benzidine;N,N'-Di-p-tolylbenzidine;N,N'-Bis(4-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine;N4,N4'-Di-p-tolyl-[1,1'-biphenyl]-4,4'-diaMine;N'-Di-(4-methyl-phenyl)-benzidine
    3. CAS NO:10311-61-2
    4. Molecular Formula: C26H24N2
    5. Molecular Weight: 364.48216
    6. EINECS: 1312995-182-4
    7. Product Categories: N/A
    8. Mol File: 10311-61-2.mol
  • Chemical Properties

    1. Melting Point: 240 °C
    2. Boiling Point: 562.5 °C at 760 mmHg
    3. Flash Point: 355.6 °C
    4. Appearance: /
    5. Density: 1.141
    6. Refractive Index: N/A
    7. Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
    8. Solubility: N/A
    9. PKA: 1.83±0.50(Predicted)
    10. CAS DataBase Reference: N,N'-Di-(4-methyl-phenyl)-benzidine(CAS DataBase Reference)
    11. NIST Chemistry Reference: N,N'-Di-(4-methyl-phenyl)-benzidine(10311-61-2)
    12. EPA Substance Registry System: N,N'-Di-(4-methyl-phenyl)-benzidine(10311-61-2)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 10311-61-2(Hazardous Substances Data)

10311-61-2 Usage

Uses

Used in Chemical Production Industry:
N,N'-Di-(4-methyl-phenyl)-benzidine is used as an intermediate in the synthesis of dyes and pigments for various applications, such as coloring textiles, plastics, and printing inks. Its chemical properties allow for the creation of a wide range of colorants with specific characteristics.
Used in Rubber and Plastics Industry:
In the rubber and plastics industry, N,N'-Di-(4-methyl-phenyl)-benzidine is utilized as an intermediate to produce materials with desired properties, such as durability, flexibility, and color stability. Its role in the manufacturing process contributes to the development of various rubber and plastic products used in everyday life.
However, due to its carcinogenic nature and the associated health risks, the use of N,N'-Di-(4-methyl-phenyl)-benzidine is subject to stringent regulations and risk management measures. The industry is encouraged to seek alternative compounds with lower toxicity and environmental impact for the production of dyes, pigments, rubber, and plastics.

Check Digit Verification of cas no

The CAS Registry Mumber 10311-61-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,3,1 and 1 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 10311-61:
(7*1)+(6*0)+(5*3)+(4*1)+(3*1)+(2*6)+(1*1)=42
42 % 10 = 2
So 10311-61-2 is a valid CAS Registry Number.

10311-61-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name N,N'-Di-p-tolylbenzidine

1.2 Other means of identification

Product number -
Other names N,N′-Di-p-tolylbenzidine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10311-61-2 SDS

10311-61-2Relevant articles and documents

Tricarbonylrhenium(I) Complexes of Dinucleating Redox-Active Pincer Ligands

Gardinier, James R.,Hewage, Jeewantha S.,Bennett, Brian,Wang, Denan,Lindeman, Sergey V.

, p. 989 - 1000 (2018)

Two homobimetallic tricarbonylrhenium(I) complexes of new redox-active dinucleating pincer ligands have been prepared to assess the impact of spacer size on the first oxidation potentials with respect to mononucleating analogues and on intramolecular elec

Metal-Free Oxidative C-C Coupling of Arylamines Using a Quinone-Based Organic Oxidant

Maddala, Sudhakar,Mallick, Sudesh,Venkatakrishnan, Parthasarathy

, p. 8958 - 8972 (2017/09/11)

A variety of arylamines are shown to undergo oxidative C-C bond formation using quinone-based chloranil/H+ reagent as the recyclable organic (metal-free) oxidant system to afford benzidines/naphthidines. Arylamines (3°/2°) designed with various substituents were employed to understand the steric as well as electronic preferences of oxidative dimerization, and a mechanism involving amine radical cation has been proposed. The tetraphenylbenzidine derivative obtained via oxidative C-C coupling has been further converted to blue-emissive hole-transporting material via a simple chemical transformation. This study highlights the preparation of novel HTMs in a simple, economic, and efficient manner.

Organic light-emitting material and method for producing an organic material

-

Page/Page column 10, (2008/06/13)

An organic light-emitting material characterized in that it is used in a light emitting layer in a green light emitting element and represented by the following general formula (1): wherein: n1 is an integer of 0 to 3; R1 is an alkyl

Silanamine derivative and process for the production thereof, and organical EL device using the said silanamine derivative

-

, (2008/06/13)

Silanamine derivatives which have the formula (I), wherein each of Ar1s and Ar3s is an optionally substituted aryl group and Ar2 is an optionally substituted arylene group, and, which are used as a material for producing an organic EL device.

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