103836-50-6Relevant articles and documents
Photolysis of Dimethylcarbamoyl Azide in the Presence of a Cyclic Aminimide
Gibson, Harry H.,Weissinger, Keith,Abashawl, Aida,Hall, Greg,Lawshae, Tom,et al.
, p. 3858 - 3861 (2007/10/02)
Dimethylcarbamoyl azide has been photolyzed in the presence of methyl isocyanate to produce the cyclic aminimide 1,1,4-trimethyl-1,2,4-triazolidine-3,5-dione 1,2-ylide (6) and the azo compound N-(dimethylcarbamoyl)-N,N'N'-trimethylazodicarboxamide (7).The azo compound 7 arises a photolytic reaction between dimethylcarbamoyl azide and aminimide 6.Mechanistic studies support a reaction path involving intermolecular-assisted loss of nitrogen from the azide as a result of interaction with aminimide 6.