104863-72-1Relevant articles and documents
Asymmetric reduction of trifluoromethyl ketones containing a sulfur functionality by the alcohol dehydrogenase from Geotrichum
Nakamura, Kaoru,Matsuda, Tomoko,Shimizu, Makoto,Fujisawa, Tamotsu
, p. 8393 - 8402 (1998)
The reduction of trifluoromethyl ketones containing a sulfur functionality by the crude alcohol dehydrogenase from Geotrichum proceeded successfully, and the corresponding optically active alcohols were synthesized with high yields and excellent enantiose
2-(2,2,2-trifluoroethylidene)-1,3-dithiane monoxide as a trifluoromethylketene equivalent
Yoshida, Suguru,Yorimitsu, Hideki,Oshima, Koichiro
supporting information; experimental part, p. 2185 - 2188 (2009/09/28)
A method to prepare 2-(2,2,2-trifluoroethylidene)-1,3-dithiane monoxide has been developed, and its interesting reactivity under Pummerer-like conditions is disclosed. The products are useful synthetic intermediates for the synthesis of α-trifluoromethyl
2-(2,2,2-Trifluoroethylidene)-1,3-dithianes. New Intermediates for the Preparation of CF3-Containing Compounds
Solberg, Jan,Benneche, Tore,Undheim, Kjell
, p. 69 - 73 (2007/10/02)
A simple and efficient synthesis of 2-(2,2,2-trifluoroethylidene)-1,3-dithianes is described.The title compounds are versatile intermediates for the preparation of trifluoromethyl derivatives.
MICROBIOLOGICAL SYNTHESIS OF VARIOUSLY PROTECTED L-GLYCERALDEHYDES IN HIGH OPTICAL PURITY
Guanti, Giuseppe,Banfi, Luca,Narisano, Enrica
, p. 3547 - 3550 (2007/10/02)
Variously protected L-glyceraldehydes have been enantioselectively synthesized through a sequence involving acylation of formylanion equivalents with glycolic acid derivatives followed by baker's yeast mediated reduction of the resulting ketones.
