105404-34-0Relevant articles and documents
1-Halosilatranes
Voronkov, M. G.,Baryshok, V. P.,Petukhov, L. P.,Rakhlin, V. I.,Mirskov, R. G.,Pestunovich, V. A.
, p. 39 - 56 (2007/10/02)
The electronic structure of 1-halosilatranes is discussed.Some new preparative methods based on hetero- and homo-lytic reactions of the silatrane and the Si- and C-substituted silatranes with halogenating reagents are described and also synthetic routes to 1-halosilatranes from certain organotrialkoxy- and organotrichlorosilanes.The electrophilic reactions of 1-iodosilatrane with ethers and esters, carbonyl compounds, alkoxysilanes and siloxanes, terminal alkynes and organomercurials have been studied