92085-71-7

Upstream product

• 102-71-6 triethanolamine 
• 2551-83-9 allyltrimethoxysilane 

Downstream Products

• 126426-31-1 C₁₅H₂₁Cl₃N₂O₅SSi 
• 54653-25-7 ethyl hex-5-enoate 
• 187737-37-7 propene 
• 63330-91-6 (E)-1-(2-phenylethenyl)-2,8,9-trioxa-5-aza-1-silabicyclo<3.3.3>undecane 
• 126383-41-3 4-Chloro-N-[2-chloro-3-(2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undec-1-yl)-propyl]-benzenesulfonamide 
• 126383-42-4 N-[2-Chloro-3-(2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undec-1-yl)-propyl]-4-methyl-benzenesulfonamide 
• 126383-40-2 N-[2-Chloro-3-(2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undec-1-yl)-propyl]-benzenesulfonamide 
• 3463-21-6 1-ethoxysilatrane 
• 105404-34-0 1-(1-oxyl-2,2,6,6-tetramethyl-³Δ-dehydropiperidyl-4)silatrane 
• 84471-19-2 1-(3-chlorophenoxy)silatrane 
• 2097-16-7 1-ethylsilatrane 
• 2097-19-0 1-phenyl-2,8,9-trioxa-5-aza-1-silabicyclo{3.3.3}undecane 
• 3463-22-7 1-phenoxysilatrane 
• 4025-80-3 1-Methoxysilatran 

Relevant academic research and scientific papers

Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins-mechanistic considerations

We have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on sto

Reactivity of hypervalent species of silicon: cleavage of the allyl-silicon bond

The reactivities of the silicon-allyl bonds in two kinds of pentacoordinated silicon species CH2=CHCH2Si(o-O2C6H4)2-NMe4+ (1) and CH2=CHCH2Si(OCH2CH2)3N (2) has been compared.In the allyl transfer to carbonyl compounds under nucleophilic conditions (NaOMe, KF or Bu4NF) and electrophilic conditions (TiCl4, AlCl3, BF3) these two species show quite different behaviour.Complex 1 is activated by nucleophiles, while for 2 transfer occurs under electrophilic conditions.These results indicate that the reactivity of these species is a function of their overall charge and geometry.