1122-17-4

Basic information

• Product Name: Dichloromaleic anhydride
• Synonyms: 3,4-dichlorofuran-2,5-quinone;2,3-Dichloromaleic anhydride 97%;2,3-DICHLOROMALEIC ANHYDRIDE;DICHLOROMALEIC ANHYDRIDE;2,3-Dichloromaleic acid anhydride;3,4-Dichloro-2,5-furandione;3,4-dichloro-5-furandione;3,4-Dichloro-furan-2,5-dione
• CAS NO: 1122-17-4
• Molecular Formula: C₄Cl₂O₃
• Molecular Weight: 166.95
• EINECS: 214-343-0
• Product Categories: Industrial/Fine Chemicals;Anhydride Monomers;Monomers;Polymer Science;Carbonyl Compounds;Carboxylic Acid Anhydrides;Organic Building Blocks
• Mol File: 1122-17-4.mol

Chemical Properties

• Melting Point: ~120 °C
• Boiling Point: 170.506 °C at 760 mmHg
• Flash Point: 74.055 °C
• Appearance: /
• Density: 1.7168 (estimate)
• Vapor Pressure: 1.46mmHg at 25°C
• Refractive Index: 1.548
• Storage Temp.: 2-8°C
• Solubility: Chloroform, Methanol (Slightly, Heated)
• BRN: 121027
• CAS DataBase Reference: Dichloromaleic anhydride(CAS DataBase Reference)
• NIST Chemistry Reference: Dichloromaleic anhydride(1122-17-4)
• EPA Substance Registry System: Dichloromaleic anhydride(1122-17-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• F: 10-21
• HazardClass: IRRITANT
• Hazardous Substances Data: 1122-17-4(Hazardous Substances Data)

Usage

Uses

Used in Agricultural Industry:
Dichloromaleic anhydride is used as a fungicide for controlling fungal infections, particularly against Botrytis cinerea, a common plant pathogen responsible for gray mold disease. Its antifungal activity helps protect crops and improve agricultural yields.
Used in Chemical Synthesis:
Dichloromaleic anhydride serves as an intermediate in the synthesis of various organic compounds and pharmaceuticals. Its unique chemical structure allows for the development of new molecules with potential applications in different industries.
Used in Material Science:
Due to its reactive nature, dichloromalic anhydride can be utilized in the modification of polymers and other materials. This can lead to the creation of new materials with enhanced properties, such as improved stability or resistance to environmental factors.

Purification Methods

Purify the anhydride by sublimation in vacuo [Katakis et al. J Chem Soc, Dalton Trans 1491 1986]. It has also been purified by Soxhlet extraction with hexane, recrystallised from CHCl3 and sublimed [MS, Relles J Org Chem 37 3630 1972]. [Beilstein 17/11 V 63.]

InChI:InChI=1/C4Cl2O3/c5-1-2(6)4(8)9-3(1)7

Upstream product

• 108-31-6 maleic anhydride 
• 15341-59-0 3,4-dichlorofuran 
• 96-02-6 2-chloromaleic anhydride 
• 608-42-4 cis-2,3-dichlorobutenedioic acid 
• 5196-32-7 dichloro-maleic acid-dichloride 
• 408332-88-7 Diethyl tartrate 
• 13821-77-7 octachloro-cyclohex-3-enone 
• 85278-93-9 1,2-dichloro-1,2-dicyanoethylene 
• 59660-63-8 3,4,5,5-tetrachloro-2,5-dihydro-2-furanone 
• 57697-64-0 mucochloric acid 
• 7697-37-2 nitric acid 
• 108-30-5 succinic acid anhydride 
• 7782-50-5 chlorine 
• 7705-08-0 iron(III) chloride 

Downstream Products

• 1114-23-4 dimethyl 2,3-dichloromaleate 
• 129-64-6 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride 
• 6903-92-0 3-Chlor-1-phenyl-4-phenylamino-pyrrolin-2,5-dion 
• 14918-69-5 2,3-dichloro-5,8-dihydroxy-[1,4]naphthoquinone 
• 1193-54-0 3,4-dichloromaleimide 
• 95319-68-9 toluene-4-sulfonyl-(1,3,3-trimethyl-2-methylene-2,3-dihydro-indol-5-yl)-maleic acid anhydride 
• 118899-25-5 toluene-4-sulfonyl-(1,3,3-trimethyl-1,3-dihydro-indol-2-ylidenemethyl)-maleic acid anhydride 
• 56962-08-4 4,5-dichlorophthalic acid 
• 58552-85-5 1,4-diphenyl-1,4-dihydro-[1,4]diphosphinine-2,3,5,6-tetracarboxylic acid 2,3;5,6-dianhydride 
• 101247-39-6 [4-(3,4-Dichloro-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-benzoylamino]-acetic acid 
• 122457-71-0 3,4-methylenedioxybenzyl hydrogen dichloromaleate 
• 127394-87-0 1-(2',4',6'-trichloro)phenylamino-3,4-dichloro-1H-pyrrole-2,5-dione 
• 101247-37-4 2-(3,4-Dichloro-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-3-phenyl-propionic acid 
• 101247-41-0 2-[2-(3,4-Dichloro-2,5-dioxo-2,5-dihydro-pyrrol-1-yl)-benzoylamino]-benzoic acid 

Related news

Novel chemistry of the imda adducts of the amides derived from Dichloromaleic anhydride (cas 1122-17-4) and β-aminomethylstyrenes09/27/2019

Reaction of amides derived from dichloromaleic anhydride and β-aminomelhylstyrenes affords unstable Diels Alder adducts, which give via competing processes a number of products including pyrrolidinones by a novel sequence of dehydrochlorination and subsequent ring-opening of a cyclohexadiene. t]detailed

Complexes of Dichloromaleic anhydride (cas 1122-17-4) with some methylbenzenes and the electron affinities of maleic anhydride and Dichloromaleic anhydride (cas 1122-17-4)09/25/2019

Isomeric 1:1 complexes and higher order complexes are formed between dichloromaleic anhydride and either durene, pentamethylbenzene or hexamethylbenzene in carbon tetrachloride solution. The electron affinities of dichloromaleic anhydride and maleic anhydride as calculated from the charge transf...detailed

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