113678-91-4Relevant articles and documents
Production of 3-vinylcatechol and physiological properties of Pseudomonas LF-3, which can assimilate styrene in a two-phase (solvent-aqueous) system
Yoshida, Yuriko,Ikura, Yoko,Kudo, Toshiaki
, p. 46 - 50 (1997)
A microorganism able to grow in mineral salt medium with styrene (0.1-10%) as a sole carbon source was isolated. The bacterium belongs to the genus Pseudomonas. Pseudomonas LF-3 used not only styrene but also toluene as a carbon source. Cell viability, total cell count, and turbidity with 0.1% showed good results. Cell viability reached 7 x 108 cells/ml with 1.0% styrene and remained near this after reaching its maximum. Maximum cell viability was 1.4 x 106 cells/ml with 1.0% styrene and 1.1 x 106 cells/ml with 10% styrene, respectively. Pseudomonas LF-3 grew on 1-phenylethanol, 2-phenylethanol, benzylalcohol, acetophenone, phenyl-1,2-ethanediol, benzoic acid, or protocatechuic acid. The degradation product from styrene was separated and identified as 3-vinylcatechol. The yellow color observed in the medium suggests a meta ring cleavage pathway.
Arene cis-Diol Dehydrogenase-Catalysed Regio- and Stereoselective Oxidation of Arene-, Cycloalkane- and Cycloalkene-cis-diols to Yield Catechols and Chiral α-Ketols
Boyd, Derek R.,Sharma, Narain D.,Berberian, M. Victoria,Cleij, Marcel,Hardacre, Christopher,Ljubez, Vera,McConville, Gareth,Stevenson, Paul J.,Kulakov, Leonid A.,Allen, Christopher C. R.
, p. 1881 - 1894 (2015)
Benzene cis-diol dehydrogenase and naphthalene cis-diol dehydrogenase enzymes, expressed in Pseudomonas putida wild-type and Escherichia coli recombinant strains, were used to investigate regioselectivity and stereoselectivity during dehydrogenations of arene, cyclic alkane and cyclic alkene vicinal cis-diols. The dehydrogenase-catalysed production of enantiopure cis-diols, α-ketols and catechols, using benzene cis-diol dehydrogenase and naphthalene cis-diol dehydrogenase, involved both kinetic resolution and asymmetric synthesis methods. The chemoenzymatic production and applications of catechol bioproducts in synthesis were investigated.
Ortho-vinylation reaction of phenols with ethyne
Yamaguchi, Masahiko,Arisawa, Mieko,Omata, Kenji,Kabuto, Kuninobu,Hirama, Masahiro,Uchimaru, Tadafumi
, p. 7298 - 7305 (2007/10/03)
Phenols were vinylated at the ortho-position with ethyne in the presence of SnCl4-Bu3N reagent. The reaction was applicable to phenols possessing either electron-donating or electron-withdrawing groups. 2,6-Divinylphenols were synthe
