114673-96-0Relevant articles and documents
An Enantiospecific Synthesis of Allosamizoline
Simpkins, Nigel S.,Stokes, Stephen,Whittle, Alan J.
, p. 2471 - 2478 (2007/10/02)
An enantiospecific synthesis of allosamizoline 4, the aglycone of the chitinase inhibitor allosamidin 3, has been achieved, starting from readily available glucosamine.The key step in the synthesis involves the cyclisation of a carbon-centred radical onto
An Enantiospecific Total Synthesis of Allosamizoline
Simpkins, Nigel S.,Stokes, Stephen,Whittle, Alan J.
, p. 793 - 796 (2007/10/02)
An enantiospecific total synthesis of allosamizoline has been accomplished in a short stereoselective sequence starting from glucosamine.
Enantiospecific total synthesis of (-)-allosamizoline, and aminocyclitol moiety of the insect chitinase inhibitor allosamidin
Nakata, Masaya,Akazawa, Seiji,Kitamura, Shuji,Tatsuta, Kuniaki
, p. 5363 - 5366 (2007/10/02)
Total synthesis of (-)-allosamizoline (2), an aminocyclitol moiety of the insect chitinase inhibitor allosamidin (1) has been enantiospecifically synthesized from D-glucosamine by using an intramolecular cycloaddition of the nitrile oxide to an olefin as a key step.
Stereocontrolled synthesis of (-)-allosamizoline using D-glucosamine as a chiral template
Takahashi, Shunya,Terayama, Hiroyuki,Kuzuhara, Hiroyoshi
, p. 5123 - 5126 (2007/10/02)
(-)-Allosamizoline (1), a core component of novel insect chitinase inhibitor, allosamidin (2), was stereoselectively synthesized from D-glucosamine (3), using an efficient ring contraction reaction as a key step.