138395-78-5Relevant articles and documents
Asymmetric desymmetrization of meso-cyclopentitol using a C2-symmetric bis-sulfoxide: A synthesis of (-)-allosamizoline
Maezaki, Naoyoshi,Sakamoto, Atsunobu,Tanaka, Tetsuaki,Iwata, Chuzo
, p. 179 - 182 (2007/10/03)
A synthesis of (-)-allosamizoline was accomplished via asymmetric desymmetrization of a meso-cyclopentitol using the C2-symmetric bis-sulfoxide 5 as a chiral auxiliary.
Enantiospecific total synthesis of (-)-allosamizoline, and aminocyclitol moiety of the insect chitinase inhibitor allosamidin
Nakata, Masaya,Akazawa, Seiji,Kitamura, Shuji,Tatsuta, Kuniaki
, p. 5363 - 5366 (2007/10/02)
Total synthesis of (-)-allosamizoline (2), an aminocyclitol moiety of the insect chitinase inhibitor allosamidin (1) has been enantiospecifically synthesized from D-glucosamine by using an intramolecular cycloaddition of the nitrile oxide to an olefin as a key step.