115224-88-9

Basic information

• Product Name: L-glycero-L-galacto-Heptitol, 2,6-anhydro-, pentaacetate
• Synonyms: L-glycero-L-galacto-Heptitol, 2,6-anhydro-, pentaacetate
• CAS NO: 115224-88-9
• Molecular Formula: C17H24 O11
• Molecular Weight: 404.37
• Mol File: 115224-88-9.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: L-glycero-L-galacto-Heptitol, 2,6-anhydro-, pentaacetate(CAS DataBase Reference)
• NIST Chemistry Reference: L-glycero-L-galacto-Heptitol, 2,6-anhydro-, pentaacetate(115224-88-9)
• EPA Substance Registry System: L-glycero-L-galacto-Heptitol, 2,6-anhydro-, pentaacetate(115224-88-9)

Safety Data

• Hazardous Substances Data: 115224-88-9(Hazardous Substances Data)

Upstream product

• 115141-20-3 Acetic acid (2R,3S,4S,5S,6S)-3,5-diacetoxy-2-acetoxymethyl-6-trimethylsilanyloxymethyl-tetrahydro-pyran-4-yl ester 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 
• 228115-81-9 Acetic acid (1S,4R,6R,7S,8R)-8-acetoxy-6-acetoxymethyl-3-oxo-2,5-dioxa-bicyclo[2.2.2]oct-7-yl ester 
• 71420-09-2 2,3,4,6-tetra-O-acetyl-2,6-anhydro-D-glycero-L-manno-heptose 
• 71420-08-1 1,3-diphenyl-2-(tetra-O-acetyl-2,6-anhydro-D-glycero-L-manno-heptosyl)imidazolidine 
• 228115-82-0 3,4,7-tri-O-acetyl-2,6-anhydro-D-glycero-L-manno-heptonic acid 
• 52443-07-9 3,4,5,7-tetra-O-acetyl-2,6-anhydro-D-glycero-L-manno-heptonitrile 
• 4163-60-4 β-D-galactose peracetate 
• 64-19-7 acetic acid 

Downstream Products

• 228115-84-2 2,6-anhydro-1,7-di-O-(p-toluenesulfonyl)-L-glycero-L-galacto-heptitol 
• 228115-85-3 2,6-anhydro-1,4,7-tri-O-(p-toluenesulfonyl)-L-glycero-L-galacto-heptitol 
• 71072-12-3 (4aS,8aR,9R,9aR,10aR)-2,7-Diphenyl-hexahydro-1,3,6,8,10-pentaoxa-anthracen-9-ol 
• 71072-13-4 Acetic acid (4aS,8aS,9R,9aS,10aR)-2,7-diphenyl-hexahydro-1,3,6,8,10-pentaoxa-anthracen-9-yl ester 
• 228115-96-6 2,6-anhydro-4-azido-1,3:5,7-di-O-benzylidene-4-deoxy-L-glycero-L-gluco-heptitol 
• 228115-94-4 2,6-anhydro-1,3:5,7-di-O-benzylidene-4-O-toluenesulfonyl-L-glycero-L-galacto-heptitol 
• 228115-86-4 C₂₄H₃₀O₁₀S₂ 

Relevant articles and documents

Coupling of anhydro-aldose tosylhydrazones with hydroxy compounds and carboxylic acids: a new route for the synthesis of C-β-d-glycopyranosylmethyl ethers and esters

Cross couplings of O-peracylated 2,6-anhydro-aldose tosylhydrazones (C-(β-d-glycopyranosyl)formaldehyde tosylhydrazones) with alcohols, phenols, and carboxylic acids were studied under thermic or photolytic conditions in the presence of K3PO4 or LiOtBu. The reactions failed with EtOH, BnOH, or tBuOH, however, (CF3)2CHOH, electron poor phenols and carboxylic acids gave the corresponding C-β-d-glycopyranosylmethyl ethers and esters, respectively, representing a new access to these glycomimetic compounds.

Synthesis studies of structural analogues of tagetitoxin: 4-O-acetyl-3- amino-1,6-anhydro-3-deoxy-D-gulose 2-phosphate

Synthetic approaches to structural analogues of tagetitoxin (1) are described. The successful route to analogue 3 (X=O) has, as a key step, protection of the cis-vicinal amino alcohol moiety of compound 7 as an N- benzylated cyclic carbamate (9). X-Ray cr

Catalytic Siloxymethylation of Glycosides by the HSiR3/CO/Co2(CO)8 Reaction. A New Entry to C-Glycosyl Compounds

The acetoxy group at the anomeric center of glycosides can be replaced with a siloxymethyl group by Co2(CO)8-catalyzed reaction with carbon monoxide and a hydrosilane.