- Understanding the desulphurization process in an ionic porous aromatic framework
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An ionic porous aromatic framework, iPAF-1, was successfully synthesized from a designed monomer with imidazolium functional groups. The iPAF-1 exhibits the highest dibenzothiophene uptake among all reported adsorptive desulphurization adsorbents. The so-
- Tian, Yuyang,Song, Jian,Zhu, Youliang,Zhao, Huanyu,Muhammad, Faheem,Ma, Tingting,Chen, Mo,Zhu, Guangshan
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- The fabrication of IMo6?iPAF-1 as an enzyme mimic in heterogeneous catalysis for oxidative desulfurization under O2or air
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Na5[IMo6O24]·3H2O and a porous aromatic framework (iPAF-1) were used to build an off-the-shelf building material (IMo6?iPAF-1) to realize the highly efficient oxidation of organic sulfurs like oxygena
- Bawa, Mbage,Jiang, Mengting,Li, Yue,Song, Jian,Tian, Yuyang,Wang, Xiaohong,Zhu, Guangshan
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supporting information
p. 9813 - 9824
(2020/06/05)
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- Synthesis of tetraarylmethanes via a Friedel-Crafts cyclization/desulfurization strategy
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Tetraarylmethanes are an important class of molecules that contain four aryl groups bonded to a central carbon atom. The shape/three-dimensionality of these molecules makes them suitable for organic light-emitting diodes (OLEDs), organic solar cells, hydrogen storage, and even drug-delivery. Despite their importance, there are only a few methods available for their preparation. Herein, we report a simple procedure for the preparation of tetraarylmethanes that involves a bismuth-catalyzed Friedel-Crafts cyclization followed by a desulfurization reaction mediated by Raney nickel.
- Griffin, Paul J.,Fava, Matthew A.,Whittaker, St. John T.,Kolonko, Kristopher J.,Catino, Arthur J.
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p. 3999 - 4002
(2018/10/02)
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