116015-72-6 Usage
Uses
Used in Organic Synthesis:
Sucrose 4,6-Methyl Orthoester is used as a synthetic intermediate for the preparation of various organic compounds. Its unique structure allows for the formation of new chemical bonds and the synthesis of complex molecules, making it a valuable component in the development of pharmaceuticals, agrochemicals, and other specialty chemicals.
Check Digit Verification of cas no
The CAS Registry Mumber 116015-72-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,6,0,1 and 5 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 116015-72:
(8*1)+(7*1)+(6*6)+(5*0)+(4*1)+(3*5)+(2*7)+(1*2)=86
86 % 10 = 6
So 116015-72-6 is a valid CAS Registry Number.
InChI:InChI=1/C15H26O12/c1-14(22-2)23-4-7-11(26-14)9(19)10(20)13(24-7)27-15(5-17)12(21)8(18)6(3-16)25-15/h6-13,16-21H,3-5H2,1-2H3/t6-,7?,8+,9?,10?,11?,12-,13?,14?,15+/m1/s1
116015-72-6Relevant articles and documents
Further examples of orthoesterification under kinetically controlled conditions. Application to the selective acylation of sucrose, maltose and α, α-trehalose
Bouchra, Mohamed,Gelas, Jacques
, p. 17 - 25 (1997)
Orthoesterification of sucrose with 1,1-dimethoxyethene under kinetic control gave 4,6-O-methoxyethylidenesucrose in 77% crude yield. Similar orthoesterification of maltose led essentially after acetylation to 1,2,3,6,2',3'-hexa-O-acetyl-4'-6'-O-methoxyethylidenemaltose. Analogous treatment of α,α-trehalose gave 2,3,2',3'-tetra-O-acetyl-4,6:4',6'-di-O- methoxyethylidene-α,α-trehalose in 47% yield. The acid-catalyzed opening of these orthoesters was studied, and these reactions were shown to give disaccharides selectively protected by acetyl groups.
