116407-32-0

Basic information

• Product Name: (1R,2R)-1,2-Diaminocyclohexane D-tartrate
• Synonyms: (1R,2R)-1,2-Diaminocyclohexane D-tartrate;(1R,2R)-Cyclohexane-1,2-diaMine (2S,3S)-2,3-dihydroxysuccinate
• CAS NO: 116407-32-0
• Molecular Formula: C₄H₆O₆*C₆H₁₄N₂
• Molecular Weight: 264.2756
• Mol File: 116407-32-0.mol

Chemical Properties

• Appearance: /
• Storage Temp.: Room temperature.
• CAS DataBase Reference: (1R,2R)-1,2-Diaminocyclohexane D-tartrate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R)-1,2-Diaminocyclohexane D-tartrate(116407-32-0)
• EPA Substance Registry System: (1R,2R)-1,2-Diaminocyclohexane D-tartrate(116407-32-0)

Safety Data

• Hazardous Substances Data: 116407-32-0(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis Industry:
(1R,2R)-1,2-Diaminocyclohexane D-tartrate is used as a reagent for the synthesis of polyimides containing a chiral diimine. Its unique stereochemistry plays a vital role in the formation of these polymers, which have potential applications in various fields due to their enhanced properties compared to their non-chiral counterparts.
Used in Materials Science:
(1R,2R)-1,2-Diaminocyclohexane D-tartrate is utilized in the development of advanced materials with specific chiral properties. The incorporation of this compound into the synthesis process allows for the creation of materials with improved characteristics, such as enhanced thermal stability, mechanical strength, and optical properties, which can be beneficial in a range of applications, including aerospace, electronics, and biomedical industries.

Upstream product

• 147-71-7 D-tartaric acid 
• 20439-47-8 (1R,2R)-1,2-diaminocyclohexane 

Downstream Products

• 220044-28-0 N-(2-hydroxy-3,5-di-tert-butylbenzaldehyde)-1-amino-2-cyclohexaneimine 
• 1030871-49-8 C₁₈H₂₇ClN₂O 
• 284497-48-9 N,N'-(1R,2R)-cyclohexane-1,2-diyl-bis-[1-(pyridine-2-yl)methanimine] 
• 284497-27-4 (1R,2R)-N,N'-bis(6-methyl-2-pyridylmethylidene)-1,2-cyclohexyldiimine 
• 1598408-97-9 (R,R)-N¹,N²-bis((5-methylfuran-2-yl)methyl)cyclohexane-1,2-diamine 
• 1598408-94-6 (1R,2R)-N,N′-bis[(5-methylfuran-2-yl)methylidene]cyclohexane-1,2-diamine 
• 1610762-32-7 (R,R)-N,N′-bis(5-methylthiophen-2-ylmethyl)cyclohexane-1,2-diamine 
• 857256-24-7 (1R,2R)-N,N'-bis(2-nitrophenyl)cyclohexane-1,2-diamine 
• 951153-76-7 N,N′-((1R,2R)-cyclohexane-1,2-diyl)bis(benzene-1,2-diamine) 
• 182368-90-7 (R,R)-N,N'-bis(3-tert-butyl-5-methylsalicylidene)-1,2-cyclohexanediamine 

Relevant articles and documents

Preparation method and application of trans-cyclohexanediamine tartrate

The invention provides a preparation method of trans-cyclohexanediamine tartrate. The preparation method comprises the steps of charging, dropwise adding of trans-cyclohexanediamine, dropwise adding of glacial acetic acid, heat-insulation reaction and cooling. The invention further provides application of the trans-cyclohexanediamine tartrate in preparation of a schiff base metallic cobalt complex. The specific rotation of the prepared trans-cyclohexanediamine tartrate is minus 11 degrees to minus 13 degrees, the content is greater than or equal to 98.0%, and the appearance of the trans-cyclohexanediamine tartrate is off-white or light yellow crystal. The yield of the prepared trans-cyclohexanediamine tartrate is 55.8-56%; and reaction conditions are mild, and the preparation method is simple to operate, is carried out under normal pressure, and is high in safety.

Instantaneous low temperature gelation by a multicomponent organogelator liquid system based on ammonium salts

A new synergistic multicomponent organogelator liquid system (MOGLS) was discovered during the standard protocol of tartaric acid-mediated racemic resolution of (±)-trans-1,2-diaminocyclohexane. The MOGLS is formed by a 0.126 M methanolic solution of (1R,2R)-(+)-1,2-diaminocyclohexane L-tartrate and 1 equiv of concentrated hydrochloric acid. Nonreversible gelation of oxygenated and nitrogenated solvents occurs efficiently at low temperature. Several features make this system unique: (1) it is a multicomponent solution where each of the five components is required for the organogelation property; (2) the multicomponent organogelator liquid system (MOGLS) is formed by simple, small, and commercially available chiral building blocks dissolved in a well-defined solvent system (MeOH/HCl/H2O); (3) the chiral building blocks are easily amenable for further modifications in structure-property relationship studies; (4) the gelation phenomenon takes place efficiently at low temperature upon warming up the isotropic solution, conversely to the typical gel preparation protocol (gel formation upon cooling down the isotropic solution); (5) the formed organic gels are not thermoreversible in spite of the noncovalent interactions that hold the 3D-fibrillar network together.