121943-56-4

Upstream product

• 97024-55-0 Methyl-<4-(4-methoxy-phenyl)-pent-4-enoat> 
• 67-56-1 methanol 
• 113194-59-5 5-(4-methoxyphenyl)-5-methyldihydrofuran-2(3H)-one 

Downstream Products

• 15146-22-2 4-methoxy-γ-methylbenzenebutanoic acid 
• 113194-61-9 2-diazo-6-(4-hydroxyphenyl)-3-heptanone 
• 113194-60-8 4-(4-hydroxyphenyl)pentanoic acid 

Relevant academic research and scientific papers

Controlling factors for C-H functionalization versus cyclopropanation of dihydronaphthalenes

"Chemical Equation Presented" Rhodium(lI)-catalyzed reactions of vinyldiazoacetates with dihydronaphthalenes were systematically studied. These substrates underwent cyclopropanantion and/or the combined C-H activation/ Cope rearrangement in good overall y

Synthesis of Four Possible Isomers of 9-(Bromomethylene)-1,2,5-trimethylspiroundeca-1,7-dien-3-one: Structure Elucidation of a Brominated Rearranged Chamigrane-Type Sesquiterpene

The first total synthesis of (5R*,6R*)- and (5R*,6S*)-9-(bromomethylene)-1,2,5-trimethylspiroundeca-1,7-dien-3-one (1a and 1b) was achieved stereoselectively.The relative configuration of C-5 and C-6 of the natural product Z-1 was elucidated as 5R* and 6R* by comparison with our synthetic samples.Keywords-9-(bromomethylene)-1,2,5-trimethylspiroundeca-1,7-dien-3-one; halogenated rearranged chamigrane-type sesquiterpene; total synthesis; structure elucidation; hydroxyspirodienone; regioselective reduction; bromomethylenation; allylic oxidation