123487-56-9

Basic information

• Product Name: 4-Pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside
• Synonyms: 4-Pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside
• CAS NO: 123487-56-9
• Molecular Formula: C₃₂H₃₈O₆
• Molecular Weight: 0
• EINECS: -0
• Mol File: 123487-56-9.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside(123487-56-9)
• EPA Substance Registry System: 4-Pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside(123487-56-9)

Safety Data

• Hazardous Substances Data: 123487-56-9(Hazardous Substances Data)

Upstream product

• 125392-62-3 3,4,6-tri-O-benzyl-β-D-mannopyranose 1,2-(pent-4-enyl orthobenzoate) 
• 150772-52-4 n-pent-4-enyl 2-O-benzoyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 821-09-0 n-Pent-4-enyl alcohol 
• 128503-36-6 (3aS,5R,6R,7S,7aS)-6,7-Bis-benzyloxy-5-benzyloxymethyl-2-methyl-2-pent-4-enyloxy-tetrahydro-[1,3]dioxolo[4,5-b]pyran 
• 647832-29-9 1,2-O-(4-penten-1-yl)-orthoacetyl-3,4,6-tri-O-acetyl-α-D-mannopyranose 
• 13242-53-0 acetobromomannose 

Downstream Products

• 123487-61-6 pent-4-enyl 2-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 150772-53-5 pent-4-enyl 2-O-(2-O-benzoyl-3,4-di-O-benzyl-6-O-(tert-butyldiphenylsilyl)-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 143706-46-1 4,5-dibromopentanyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 123487-57-0 Chloro-acetic acid (2S,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-pent-4-enyloxy-tetrahydro-pyran-3-yl ester 
• 166592-78-5 ((2S,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-diisopropyl-pent-4-enyloxy-silane 
• 117841-64-2 (pent-4′-enyl) 2,3,4,6-tetra-O-benzyl-α-D-mannopyranoside 
• 647832-35-7 (2R,3R,4S,5S,6S)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-(3,5-dimethoxy-benzyloxy)-6-pent-4-enyloxy-tetrahydro-pyran 
• 647832-30-2 (2R,3R,4S,5S,6S)-3,4-Bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-5-(3,4,5-trimethoxy-benzyloxy)-tetrahydro-pyran 
• 175355-41-6 pent-4-enyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 104639-36-3 3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 150772-63-7 pent-4-enyl 2-O-(3,4-di-O-benzyl-6-O-(tert-butyldiphenylsilyl)-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 157253-29-7 Dibromopentanyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 157253-28-6 Dibromopentanyl O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 175355-43-8 C₆₈H₇₉Br₂ClO₂₁ 

Relevant articles and documents

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Regioselective mannosylations of a myoinositol acceptor diol are readily achieved by Lewis acid mediated iodinolysis of n-pentenyl ortho-esters. The procedure affords a psuedotrisaccharide to which the phosphoglyceryl and other lipid residues are added le

Intramolecular C-glycosylation of 2-O-benzylated pentenyl mannopyranosides: Remarkable 1,2-trans stereoselectivity

The IDCP-promoted intramolecular C-glycosylation of pentenyl α-mannopyranosides carrying, at O-2, an activated benzyl group gave, unexpectedly, the 1,2-trans-fused bicyclic product which corresponds to an α-C-aryl mannopyranose derivative. This remarkable, strained C-glycosyl compound was rapidly epimerized to the more stable 1,2-cis product on treatment with BF3·Et2O. The IDCP-reaction product could be elaborated into a 2-(α-C-mannopyranosyl)-3,4,5-trimethoxybenzyl alcohol derivative.

Studies related to synthesis of glycophosphatidylinositol membrane-bound protein anchors. 5. n-pentenyl ortho esters for mannan components

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