104639-36-3

Upstream product

• 74372-91-1 2,3,4,6-tri-O-benzyl-α-D-glucopyranosyl chloride 
• 20672-66-6 3,4,6-tri-O-benzyl-D-mannopyranose 
• 124684-91-9 2-O-acetyl-3,4,6-tri-O-benzyl-1-deoxy-α-D-mannopyranosyl fluoride 
• 123487-56-9 pent-4-enyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 129214-38-6 2-O-acetyl-3,4,6-tri-O-benzyl-D-mannopyranoside 
• 68681-00-5 3,4,6-tri-O-benzyl-1,2-O-<1-(R)-methoxyethylidene>-β-D-mannopyranose 
• 146864-77-9 3,4,6-tri-O-benzyl-1,2-O-(exo-methoxyethylidene)-β-D-mannopyranose 
• 16697-49-7 3,4,6-tri-O-benzyl-1,2-O-(methoxyethylidene)-β-D-mannopyranose 

Downstream Products

• 74372-90-0 3,4,6-tri-O-benzyl-D-glucal epoxide 
• 231284-57-4 C₆₉H₇₁FO₁₂ 
• 231284-64-3 C₆₉H₇₁FO₁₂ 
• 358351-59-4 2-O-allyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 451463-08-4 (Z)-2-O-prop-1'-enyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 112330-11-7 (3,4,6-tri-O-benzyI-β-D-mannopyranosyl)-(1→6)-1,2,3,4-di-O-isoprpopylidene-α-D-galactopyranoside 
• 244282-24-4 cyclohexyl 3,4,6-tri-O-benzyl-β-D-mannopyranoside 
• 358351-68-5 2-O-(2-iodo-1-methoxypropyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-73-2 2-O-(1-cyclohexyloxy-2-iodopropyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-74-3 2-O-(1-(1,2:3,4-di-O-isopropylidene-α-D-galactopyranos-6-O-yl)-2-iodopropyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-76-5 2-O-(2-iodo-1-(methyl-2-O-benzyl-4-6-O-benzylidene-α-D-mannopyranosid-3-O-yl)-propyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-77-6 2-O-(2-iodo-1-(methyl-2,3,6-tri-O-benzyl-α-D-mannopyranosid-4-O-yl)-propyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-75-4 2-O-(2-iodo-1-(methyl-2,3,4-tri-O-benzyl-α-D-mannopyranosid-6-O-yl)-propyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 

Relevant academic research and scientific papers

CHEMICAL SYNTHESIS OF A (12)-D-GLUCOPYRANAN

1,2-Anhydro-3,4,6-tri-O-benzyl-α-D-glucopyranose was polymerized with a number of Lewis acids.Phosphorus pentafluoride at -60 deg C caused polymerization to a product rich in β linkages.Other Lewis acids at higher temperatures gave perbenzylated polysaccharides of lower molecular weight with less stereoselectivity.Debenzylation of the most-regular derivative gave a polysaccharide whose specific rotation was +14.7 degree and whose (13)C-n.m.r. spectrum had six absorptions corresponding to those of natural (12)-β-D-glucopyranans and additional minor peaks presumably due to some α-anomeric configurations.It was estimated to have ca. 90percent of β linkages.

An anionic inositol phosphate glycan pseudotetrasaccharide exhibits high insulin-mimetic activity in rat adipocytes

Inositol phosphate glycan pseudotetrasaccharides consisting of man-(α1-6)-man-(α1-4)-glcN-(α,β1-6)-myo-inositol-1, 2-cyclic phosphate possessing a sulfate group at either O-6 (compounds 3α,β) or O-2 (compounds 4α,β) of the terminal mannose have been prepa

Glycosyl fluorides from n-pentenyl-related glycosyl donors-application to glycosylation strategies

n-Pentenyl glycosides (NPGs) and n-pentenyl orthoesters (NPOEs) have been transformed into glycosyl fluorides by a variety of methods. In the case of NPGs, Barluenga's reagent, bis(pyridinium)iodonium(I)tetrafluoroborate (IPy 2BF4),

Ready transformation of partially unprotected thioglycosides into glycosyl fluorides mediated by NIS/HF-pyridine or ET3N·3HF

The transformation of partially unprotected phenyl 1-thioglycosides into glycosyl fluorides can be conveniently carried out by treatment with NIS in the presence of HF-pyridine. Other sources of halonium ions such as NBS, IDCP, have also been employed. Th

IPy2BF4/HF-pyridine: A new combination of reagents for the transformation of partially unprotected thioglycosides and n-pentenyl glycosides to glycosyl fluorides

(Chemical Equation Presented) The combination of bis(pyridinium)iodonium (I) tetrafluoroborate (IPy2BF4), and hydrogen fluoride pyridine (HF-py) forms an iodine monofluoride (IF) synthetic equivalent that can be used in the preparati

Allyl protecting group mediated intramolecular aglycon delivery (IAD) of glycosyl fluorides

Stereospecific 1,2-cis-glycosylation of 2-O-allyl protected glucosyl and mannosyl fluorides can be achieved via a sequence of allyl isomerization, N-iodosuccinimide mediated tethering, and intramolecular aglycon delivery (IAD). Fluoride is advantageous as

Stereospecific synthesis of 1,2-cis glycosides by allyl-mediated intramolecular aglycon delivery. 2.The use of glycosyl fluorides.

[reaction: see text] Stereospecific 1,2-cis glycosylation of 2-O-allyl-protected glucosyl and mannosyl fluorides via a sequence of allyl isomerization, N-iodosuccinimide-mediated tethering, and intramolecular aglycon delivery (IAD) is reported. The use of