126-64-7

Basic information

• Product Name: LINALYL BENZOATE
• Synonyms: 3,7-dimethyl-1,6-octadien-3-ylbenzoate;6-octadien-3-ol,3,7-dimethyl-benzoate;benzoicacid,linalylester;Linalylbenzoat;1,6-OCTADIEN-3-OL, 3,7-DIMETHYL-, BENZOATE,94%, GLC;Benzoic acid 1,5-dimethyl-1-vinyl-4-hexenyl ester;Benzoic acid 3,7-dimethyl-1,6-octadien-3-yl ester;3,7-diMethylocta-1,6-dien-3-yl benzoate
• CAS NO: 126-64-7
• Molecular Formula: C₁₇H₂₂O₂
• Molecular Weight: 258.36
• EINECS: 204-796-2
• Product Categories: Alphabetical Listings;Flavors and Fragrances;I-L
• Mol File: 126-64-7.mol

Chemical Properties

• Boiling Point: 213 °C(lit.)
• Flash Point: >230 °F
• Appearance: yellowish to amber liquid with a heavy, floral, balsamic, fruity odour
• Density: 0.98 g/mL at 25 °C(lit.)
• Vapor Pressure: 4.79E-05mmHg at 25°C
• Refractive Index: n20/D 1.508(lit.)
• CAS DataBase Reference: LINALYL BENZOATE(CAS DataBase Reference)
• NIST Chemistry Reference: LINALYL BENZOATE(126-64-7)
• EPA Substance Registry System: LINALYL BENZOATE(126-64-7)

Safety Data

• WGK Germany: 2
• RTECS: DH3300000
• Hazardous Substances Data: 126-64-7(Hazardous Substances Data)

Usage

Uses

Used in Fragrance Industry:
Linalyl benzoate is used as a fragrance ingredient for its heavy floral, balsamic, and fruity scent. It is commonly used in perfumes, colognes, and other scented products to provide a pleasant and long-lasting aroma.
Used in Flavor Industry:
Linalyl benzoate is also used as a flavoring agent in the food and beverage industry. Its unique scent profile makes it suitable for enhancing the taste of various products, such as beverages, confectionery, and baked goods.
Used in Cosmetics Industry:
In the cosmetics industry, linalyl benzoate is used as a scent enhancer and fixative in various personal care products, such as lotions, creams, and soaps. Its ability to provide a long-lasting fragrance makes it a valuable addition to these products.
Used in Aromatherapy:
Linalyl benzoate is utilized in aromatherapy for its calming and soothing properties. Its floral and fruity scent can help create a relaxing atmosphere and promote a sense of well-being.

Preparation

From linalool and benzoyl chloride in the presence of tuberose.

InChI:InChI=1/C17H22O2/c1-5-17(4,13-9-10-14(2)3)19-16(18)15-11-7-6-8-12-15/h5-8,10-12H,1,9,13H2,2-4H3

Upstream product

• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 2902-69-4 2,2,2-trichloroacetophenone 
• 98-88-4 benzoyl chloride 

Downstream Products

• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 53834-70-1 (5E)-3-hydroxy-3,7-dimethyl-3-hydroxy-1,5,7-octatriene 
• 562107-63-5 6-chloro-3,7-dimethyl-1,7-octadien-3-yl benzoate 

Relevant articles and documents

A practical and convenient synthesis of hotrienol, an excellent fruity smelling compound

The practical and convenient synthesis of hotrienol, which is an excellent fruity smelling compound, has been performed by the ene-type chlorination of linalyl acetate and then dehydrochlorinated by lithium bromide and lithium carbonate in DMF, followed by hydrolysis in three steps with an overall yield of 55%.