53834-70-1

Usage

Uses

Used in Fragrance and Flavor Industry:
Geraniol is used as a key component in the fragrance and flavor industry for its sweet, floral aroma. It is widely used to add a pleasant scent to various products, including perfumes, soaps, and candles.
Used in Cosmetics and Pharmaceuticals:
Geraniol is used as an active ingredient in cosmetics and pharmaceuticals due to its antioxidant, antimicrobial, and anti-inflammatory properties. It is commonly found in skincare products, such as creams and lotions, to provide various benefits to the skin.
Used in Pest Control Products:
Geraniol is used as a natural insect repellant in various pest control products. Its ability to repel insects makes it a popular choice for use in mosquito repellents and other insect control applications.
Used in Antioxidant Applications:
Geraniol is used as an antioxidant in the food and pharmaceutical industries to help prevent the oxidation of fats and oils, thereby extending the shelf life of products and maintaining their quality.
Used in Antimicrobial Applications:
Geraniol is used as an antimicrobial agent in various industries, including the food and pharmaceutical sectors, to inhibit the growth of bacteria, fungi, and other microorganisms, ensuring the safety and quality of products.
Used in Anti-Inflammatory Applications:
Geraniol is used in the pharmaceutical industry as an anti-inflammatory agent to help reduce inflammation and alleviate pain associated with various conditions, such as arthritis and other inflammatory disorders.

InChI:InChI=1/C10H16O/c1-5-10(4,11)8-6-7-9(2)3/h5-7,11H,1-2,8H2,3-4H3/b7-6+

Upstream product

• 40814-09-3 3-hydroxy-3-methyl-pent-4-enal 
• 4303-59-7 2-methylallyltriphenylphosphonium chloride 
• 75654-19-2 3,7-Dimethyl-1,6-octadien-3,5-diol 
• 78-94-4 methyl vinyl ketone 
• 1826-67-1 vinyl magnesium bromide 
• 67-64-1 acetone 
• 53771-60-1 3,7-dimethyl-1,5(E),7-octatrien-3-yl acetate 
• 562107-64-6 3,7-dimethyl-1,5(E),7-octatrien-3-yl propionate 
• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 144-39-8 3,7-dimethyl-1,6-octadien-3-yl propionate 
• 115-95-7 linalool acetate 
• 78-35-3 linalool isobutanoate 
• 53799-27-2 5,5-dimethoxy-3-methyl-pent-1-en-3-ol 
• 64661-54-7 6-hydroxy-2,6-dimethyl-octa-2,7-dien-4-one 

Downstream Products

• 1786-08-9 3,6-dihydro-4-methyl-2-(2-methyl-1-propenyl)–2H-pyran 

Relevant academic research and scientific papers

Synthesis of (+/-)-Hotrienol and (+/-)-Santolina Alcohol via Cyclopropenes

A short synthesis of the title monoterpenols via cyclopropylcarbinyl-homoallyl rearrangement of adducts which are themselves produced by tandem addition of vinylmagnesium bromide and an appropriate carbonyl compound to the cyclopropenes (1) is described.

A practical and convenient synthesis of hotrienol, an excellent fruity smelling compound

The practical and convenient synthesis of hotrienol, which is an excellent fruity smelling compound, has been performed by the ene-type chlorination of linalyl acetate and then dehydrochlorinated by lithium bromide and lithium carbonate in DMF, followed by hydrolysis in three steps with an overall yield of 55%.

Regioselective synthesis of substituted (3E)-1,3-dienes from chelated allyl-ironcarbene complexes and potassium enoxyborates

The addition of potassium enoxyborates to the chelated allyl-ironcarbene complex 1 leads to the corresponding η-(3E)-1,3-diene complexes 2 in fair yields. Complexes 2 can be demetalated with ceric ammonium nitrate (CAN) to give unrearranged (3E)-6-oxo-1.3-dienes 3. Prior to decomplexation, the carbonyl group can be further modified. This is demonstrated by the syntheses of the natural terpene alcohol hotrienol and of a complexed methylene- separated dienyne. Potassium enoxyborates are superior to lithium enolates as they are readily prepared in situ from a variety of aldehydes and ketones which do not form sufficiently stable lithium derivatives. In contrast to lithium enolates, only C- C coupling products derived from the 'kinetic' regioisomers are formed from unsymmetrical aliphatic ketones.

REGIOSELECTIVITY AND SYNTHETIC APPLICATION OF THE HYDROALUMINATION OF 2-METHYL-1-ALKEN-3-YN-6-OLS. UNEXPECTED INVERSION OF CONFIGURATION IN THE SUBSTITUTIVE METHYLATION OF (Z)-3-IODO-2-METHYL-1,3-ALKADIEN-6-OLS

With the use of the deuterated reagents LiAlD3(OCH)3 and D2O, and also of electrophilic iodination, the regioselectivity of the hydroalumination of β-enynols with lithium trihydridomethoxyaluminate was studied.Attack by the hydride ion goes to the extent of 90percent at the Cβ atom of the enynols.The synthesis of the natural monoterpenol (+/-)-hotrienol and allied compounds was carried out.By a combination of hydroalumination-iodination and substitutive methylation a new method was developed for the building of the (Z)-2,3-dimethyl-1,3-diene fragment.The unexpected complete (90-95percent) inversion of the Z-double bond in the methylation of iodo dienols with lithiium dimethylcuprate was established.

Structure and the Synthesis of Novel Constituents of Yudzu Peel Oil and Their Conversion to Related Monoterpenes

Two novel minor components isolated from yudzu peel oil were characterized as monoterpene β-ketols, 1 and 3, by their synthesis, and they were converted to related monoterpenes, dihydroneroloxide (9) neroloxide (10) and ho-trienol (11).