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129115-89-5

2,5-Anhydro-3,4-dibenzyl-D-glucitol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 129115-89-5 Structure

  • Basic information

    1. Product Name: 2,5-Anhydro-3,4-dibenzyl-D-glucitol
    2. Synonyms: 2,5-Anhydro-3,4-dibenzyl-D-glucitol;2,5-Anhydro-3,4-bis-O-(phenylMethyl)-D-glucitol
    3. CAS NO:129115-89-5
    4. Molecular Formula: C20H24O5
    5. Molecular Weight: 344.40156
    6. EINECS: N/A
    7. Product Categories: Carbohydrates & Derivatives;Intermediates
    8. Mol File: 129115-89-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: Dichloromethane, Ether
    9. CAS DataBase Reference: 2,5-Anhydro-3,4-dibenzyl-D-glucitol(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2,5-Anhydro-3,4-dibenzyl-D-glucitol(129115-89-5)
    11. EPA Substance Registry System: 2,5-Anhydro-3,4-dibenzyl-D-glucitol(129115-89-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 129115-89-5(Hazardous Substances Data)

129115-89-5 Usage

Chemical Properties

Yellow Oil

Uses

Protected D-Glucitol.

Check Digit Verification of cas no

The CAS Registry Mumber 129115-89-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,9,1,1 and 5 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 129115-89:
(8*1)+(7*2)+(6*9)+(5*1)+(4*1)+(3*5)+(2*8)+(1*9)=125
125 % 10 = 5
So 129115-89-5 is a valid CAS Registry Number.

129115-89-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name [(2S,3R,4R,5R)-5-(hydroxymethyl)-3,4-bis(phenylmethoxy)oxolan-2-yl]methanol

1.2 Other means of identification

Product number -
Other names 3,4-dibenzyloxy-2,5-dihydroxymethyltetrahydrofuran

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:129115-89-5 SDS

129115-89-5Relevant articles and documents

Simple and efficient synthesis of 2,5-anhydro-d-glucitol

Arag?o-Leoneti, Valquiria,Carvalho, Ivone

, p. 1087 - 1089 (2013/04/10)

The synthesis of 2,5-anhydro-d-glucitol is described via intramolecular cyclization of diepoxide using ammonium formate in MeOH by a microwave-assisted reaction. The overall yield was 32% from d-mannitol derivative involving seven steps.

A general oxidative cyclization of 1,5-dienes using catalytic osmium tetroxide

Donohoe, Timothy J.,Butterworth, Sam

, p. 948 - 951 (2007/10/03)

Dihydroxylation of 1,5-dienes under acidic conditions is sufficient to induce an efficient oxidative cyclization that produces stereochemically defined tetrahydrofurans in one step [Eq. (1)]. This method is very general and efficient for a range of dienes

Preparation of 2,5-anhydrohexitols (part I). Silicon-directed stereocontrolled cyclization

Van Delft, Floris L.,Valentijn, A. Rob P.M.,Van Der Marel, Gijs A.,Van Boom, Jacques H.

, p. 165 - 190 (2007/10/03)

Stereoselective chain-extension of carbohydrate aldehydes with the hydroxymethylating reagent (dimethylphenylsilyl)methylmagnesium chloride (1) followed by acid-mediated cyclization gives access to 2,5-anhydro-hexitols. The stereoselectivity of the ring closure depends on the nature of the acid, i.e., treatment with excess BF3·Et2O or catalytic H2SO4 leads to tetrahydrofurans with 2,3-cis or 2,3-trans configuration, respectively. Concomitant elimination is effectively suppressed in case of cyclisation of the more sterically hindered isopropyl substituted silanes.

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