111555-72-7Relevant academic research and scientific papers
Applications of Cyclic Sulfates of vic-Diols: Synthesis of Episulfides, Olefins, and Thio Sugars
Calvo-Flores, Francisco G.,Garcia-Mendoza, Pilar,Hernandez-Mateo, Fernando,Isac-Garcia, Joaquin,Santoyo-Gonzalez, Francisco
, p. 3944 - 3961 (2007/10/03)
A new efficient and expeditious one-pot synthesis of thiiranes and olefins from cyclic sulfates of inc-diols is described. Opening of cyclic sulfates with potassium thioacetate or potassium thiocyanate followed by treatment with sodium methoxide led to ep
A Simple Synthesis of R,R-3,4-Dibenzyloxy-threo-hexa-1,5-diene (R,R-Divinylglycol) from D-Mannitol
Gurjar, M. K.,Pawar, S. M.
, p. 55 - 56 (2007/10/02)
Synthesis of R,R-divinylglycol (1) from D-mannitol (2) involves (i) conversion of 2 into (1,2:5,6)-di-O-isopropylidene-D-mannitol (3); (ii) benzylation of 3 to the corresponding 3,4-dibenzyloxy derivative (4); (iii) hydrolysis of 4 to a tetrol and its con
A Short Synthesis of d,l-exo-Brevicomin from Divinylglycol
Kuefner, Ulrike,Schmidt, Richard R.
, p. 1060 - 1062 (2007/10/02)
d,l-exo-Brevicomin is obtained from meso-divinylglycol via bis-O-benzylation, selective ω-hydroxylation of one double bond, oxidation of the hydroxymethyl group to the aldehyde stage, chain extension at the aldehyde function by Wittig reaction, and hydrog
