132203-71-5

Basic information

• Product Name: (+)-TRANS-MYRTANOL
• Synonyms: (1R,2R)-10-PINANOL;(1R,2R)-6,6-DIMETHYLBICYCLO[3.1.1]HEPTANE-2-METHANOL;(+)-TRANS-MYRTANOL;(+)-TRANS-MYRTANOL, TERPENE STANDARD;MYRTANOL, -(-)-trans-(SG);(1R,2R)-10-Pinanol, (1R,2R)-6,6-Dimethylbicyclo[3.1.1]heptane-2-methanol
• CAS NO: 132203-71-5
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.25
• EINECS: 258-499-8
• Mol File: 132203-71-5.mol

Chemical Properties

• Boiling Point: 219.5°C at 760 mmHg
• Flash Point: 86 °C
• Appearance: /
• Density: 0.973 g/mL at 20 °C(lit.)
• Vapor Pressure: 0.0249mmHg at 25°C
• Refractive Index: n20/D 1.488
• Storage Temp.: 2-8°C
• PKA: 14.99±0.10(Predicted)
• CAS DataBase Reference: (+)-TRANS-MYRTANOL(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-TRANS-MYRTANOL(132203-71-5)
• EPA Substance Registry System: (+)-TRANS-MYRTANOL(132203-71-5)

Safety Data

• Safety Statements: 23-24/25
• RIDADR: UN 1993 / PGIII
• WGK Germany: 3
• F: 10-23
• Hazardous Substances Data: 132203-71-5(Hazardous Substances Data)

Usage

Uses

Used in Perfumery Industry:
(+)-TRANS-MYRTANOL is used as a fragrance ingredient for its fresh, clean, and sweet scent, adding a floral and woody note to perfumes and other scented products.
Used in Skincare and Cosmetic Products:
(+)-TRANS-MYRTANOL is used as a fragrance ingredient in skincare and cosmetic products for its pleasant scent and ability to enhance the overall fragrance profile, while also being considered safe for use in these applications.
Used in Essential Oils:
(+)-TRANS-MYRTANOL is found in essential oils, where it contributes to the overall aroma and provides a fresh, clean scent to various products.

InChI:InChI=1/C10H18O/c1-10(2)8-4-3-7(6-11)9(10)5-8/h7-9,11H,3-6H2,1-2H3/t7-,8+,9+/m0/s1

Upstream product

• 23727-16-4 myrtenal 
• 6712-78-3 myrtenol 
• 1118071-19-4 2-chloromethyl-6,6-dimethylbicyclo[3.1.1]heptane 
• 515-00-4 (+/-)-myrtenol 
• 177698-19-0 Beta-pinene 
• 127-91-3 (1R,5R)-(+)-β-pinene 
• 127-91-3 (1R/S,5R/S)-6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane 
• 18172-67-3 beta-pinene 
• 33741-30-9 methyl (1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carboxylate 
• 64-19-7 acetic acid 
• 64-17-5 ethanol 
• 33741-31-0 (1R,2S)-pinan-10-oic acid methyl ester 
• 601-74-1 (1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carboxylic acid 

Downstream Products

• 4764-14-1 (+/-)-Myrtanal 
• 4764-14-1 (+/-)-Isomyrtanal 
• 29021-36-1 (1R)-10-Acetoxy-cis-pinan 
• 81510-28-3 (1R,2R,5R)-2-[2-(Diphenyl-phosphinoyl)-ethoxymethyl]-6,6-dimethyl-bicyclo[3.1.1]heptane 
• 4764-14-1 cis-myrtanal 
• 127-92-4 6,6-Dimethyl-bicyclo<3.1.1>heptan 
• 4764-14-1 (-)-cis-myrtanal 
• 590410-99-4 (1R,2R,5R)-trans-myrtanyl tosylate 
• 16750-96-2 trans-Myrtanyl-tosylat 
• 81510-31-8 [2-((1R,2R,5R)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-ylmethoxy)-ethyl]-diphenyl-phosphane 

Relevant articles and documents

Visible-Light-Mediated Aerobic Oxidation of Organoboron Compounds Using in Situ Generated Hydrogen Peroxide

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Development of a flow method for the hydroboration/oxidation of olefins

A method for the continuous preparation of alcohols by hydroboration/oxidation of olefins using flow techniques is described. The process allows the isolation of up to 120 mmol h-1 of the desired alcohol in a very rapid manner with good functional group tolerance. The flow setup can be modified to perform a continuous extraction of the desired alcohol from the biphasic mixture produced by the reaction. This journal is

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PS-COD and PS-9-BBN: Polymer-supported reagents for solution-phase parallel synthesis

(Chemical Equation Presented) 1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity to 9-BBN in olefin hydroboration.

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A method of hydroborating an alkene or alkyne, or reducing an organic functionality, oxidizing primary and secondary alcohols using a fluorous borane-sulfide is disclosed. The method includes regeneration and recycling the fluorous borane-sulfide.

Dod-S-Me and methyl 6-morpholinohexyl sulfide (MMS) as new odorless borane carriers

Odorless Dod-S-Me (1) and MMS (3) are developed as efficient borane carriers. The yields of hydroborations and reductions with borane complex 2 of 1 are very high and the recovery of 1 after the reaction is quantitative. The borane complexes 4 and 5 of 3 are also useful. In the latter case chromatographic separation is unnecessary when excess oxidizing agent (alkaline H2O2) is used after hydroboration.

Molecular Addition Compounds. 17. Borane and Chloroborane Adducts with Organic Sulfides for Hydroboration

The following sulfides have been examined as borane carriers in comparison with dimethyl sulfide and 1,4-oxathiane: tert-butyl methyl sulfide, isoamyl methyl sulfide, ethyl isoamyl sulfide, tert-butyl isoamyl sulfide, diisoamyl sulfide, tetrahydrothiophene, tetrahydro-thiopyran, thioanisole, 3-ethylthiotetrahydrofuran, bis(3-tetrahydrofuryl) sulfide, and bis(2-methoxyethyl) sulfide. Their complexing ability toward borane increases in the following order: thioanisole 3, is stable over prolonged periods at room temperature. The sulfide can be recovered from hydroboration-oxidation products by distillation. Consequently, diisoamyl sulfide is a new promising borane carrier. Bis(2-methoxyethyl) sulfide, easily synthesized from the low cost thiodiethanol, is three times more soluble in water than 1,4-oxathiane. Its borane adduct is 6.0 M in BH3 and can substitute for more expensive borane-1,4-oxathiane in hydroboration reactions. Applications of these new borane adducts in the synthesis of mono- and dichloroborane adducts was also studied. The equilibrium ratios observed for the new chloroborane adducts were similar to that observed for dimethyl sulfide adducts. However, the hydroboration of 1-octene with these new chloroborane adducts are much faster than the corresponding adducts of dimethyl sulfide, which are currently used extensively.

Novel Reduction of Carboxylic Acids and Hydroboration of Olefins by Electrolysis of Sodium Borohydride

Electrochemical oxidation of sodium borohydride in diglyme containing aliphatic or aromatic carboxylic acids followed by acid-catalyzed hydrolysis afforded the corresponding primary alcohols in good yields.Furthermore, similar electrochemical oxidation in the presence of a variety of olefins instead of carboxylic acids, followed by treatment with alkaline-hydrogen peroxide, brought about novel electrochemical hydroboration to give the corresponding alcohols regio- and stereoselectively in good yields.

Novel Method for Hydroboration of Olefins Using Electrolysis

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