134235-79-3

Basic information

• Product Name: 3-Cyclohexene-1-carboxylicacid,4-methyl-,methylester,(S)-(9CI)
• Synonyms: 3-Cyclohexene-1-carboxylicacid,4-methyl-,methylester,(S)-(9CI)
• CAS NO: 134235-79-3
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.21
• Product Categories: CARBOXYLICESTER
• Mol File: 134235-79-3.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Cyclohexene-1-carboxylicacid,4-methyl-,methylester,(S)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-carboxylicacid,4-methyl-,methylester,(S)-(9CI)(134235-79-3)
• EPA Substance Registry System: 3-Cyclohexene-1-carboxylicacid,4-methyl-,methylester,(S)-(9CI)(134235-79-3)

Safety Data

• Hazardous Substances Data: 134235-79-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 134166-10-2 (S)-3-(4-methylcyclohex-3-enecarbonyl)oxazolidin-2-one 
• 292638-85-8 acrylic acid methyl ester 
• 78-79-5 isoprene 

Downstream Products

• 102208-60-6 (S)-4-methyl-3-cyclohexene-1-carboxylic acid 

Relevant articles and documents

Enantioselective Diels-Alder Reactions of Carboxylic Ester Dienophiles Catalysed by Titanium-Based Chiral Lewis Acid

A new titanium-based chiral Lewis acid 1 has been developed using (1R,2R)-1,2-bis-(2-methoxyphenyl)-ethane-1,2-diol as a chiral vicinal diol ligand. This chiral catalyst was found to exhibit uniformly high enantioselectivity towards carboxylic ester dienophiles in Diels-Alder reactions. The chiral vicinal ligand (1R,2R)-1,2-bis-(2-methoxyphenyl)-ethane-1,2-diol is inexpensive and is easily accessible.

Asymmetric Diels-Alder Reactions of an Acrylic Acid Derivative Using a Chiral Titanium Catalyst

Asymmetric Diels-Alder reactions of an acrylic acid derivative using a catalytic amount of a chiral titanium reagent were performed with several dienes.The titanium catalyst was prepared by the alkoxy exchange between dichlorodiisopropoxytitanium(IV) and a chiral 1,4-diol derived from (2R,3R)-tartrate.By the use of the titanium catalyst, the reaction between 3-acryloyl-1,3-oxazolidin-2-one and dienes proceeded in a toluene-petroleum ether mixture in the presence of Molecular Sieves 4A to afford the Diels-Alder adducts in 72-100percent yields and 88 - >96percent enantioselectivity.This reaction can be applied to a diene containing a hetero atom such as 2-ethylthio-1,3-butadiene, which affords the Diels-Alder adduct in a high optical purity.In this paper are also described the methods for determining the optical purities of the obtained 4-substituted 3-cyclohexenecarboxylic acid derivatives.