136152-26-6Relevant articles and documents
Unraveling the synthesis of homoleptic [Ag(N, N -diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling
Beillard, Audrey,Bantreil, Xavier,Métro, Thomas-Xavier,Martinez, Jean,Lamaty, Frédéric
, p. 17859 - 17866 (2016/11/18)
A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(i) complexes featuring N,N-diarylimidazol(idin)ene ligands and non-coordinating tetrafluoroborate or hexafluorophosphate counter anions. Comparison with syntheses in solution clearly demonstrated the superiority of the ball-milling conditions.