137032-93-0Relevant articles and documents
Stereoselective synthesis of cis-decalins via Diels-Alder and double Michael addition of substituted Nazarov reagents
Lavallee, Jean-Francois,Spino, Claude,Ruel, Rejean,Hogan, Keith T.,Deslongchamps, Pierre
, p. 1406 - 1426 (2007/10/02)
The base-catalyzed cycloaddition and double Michael cyclization of sustituted Nazarov reagents and 1-phenyl-sulfinyl analogs, with 2-carbomethoxy-2-cyclohexen-1-one 1 yielding cis-decalins is reported.The reaction is highly stereoselective affording cis,c
Facile Access to 2-Alkylidene 3-Oxy Propanals and Propionic Acids from Conjugated Enals
Huot, Jean-Francois,Outurquin, Francis,Paulmier, Claude
, p. 1599 - 1602 (2007/10/02)
Conjugated enals or their methyl acetals react with benzeneselenyl chloride in the presence of oxygen nucleophile to give Michael-type adducts.The latter are oxidized into 2-alkylidene 3-oxy propanals and propionic acids.