109380-07-6

Basic information

• Product Name: (S)-2-bromo-cyclohex-2-en-1-ol
• CAS NO: 109380-07-6
• Molecular Weight: 177.041
• Mol File: 109380-07-6.mol
• Article Data: 31

Chemical Properties

• CAS DataBase Reference: (S)-2-bromo-cyclohex-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-bromo-cyclohex-2-en-1-ol(109380-07-6)
• EPA Substance Registry System: (S)-2-bromo-cyclohex-2-en-1-ol(109380-07-6)

Safety Data

• Hazardous Substances Data: 109380-07-6(Hazardous Substances Data)

Upstream product

• 123-75-1 pyrrolidine 
• 14310-04-4 2-bromocyclohex-2-en-1-yl acetate 
• 97861-66-0 ethyl 2-bromo-2-cyclohexenyl carbonate 
• 2568-36-7 6,6-dibromobicylo[3.1.0]hexane 
• 609-02-9 methyl-malonic acid dimethylester 
• 930-68-7 cyclohexenone 
• 168985-70-4 2,3-dibromocyclohexanone 
• 50870-61-6 2-bromocyclohex-2-en-1-one 
• 109380-07-6 2-bromocyclohex-2-en-1-ol 
• 61426-49-1 (S)-2-bromo-cyclohex-2-en-1-ol 

Downstream Products

• 16253-84-2 1-Bromo-6-tert-butoxy-cyclohexene 
• 109380-16-7 Acetic acid (R)-2-bromo-cyclohex-2-enyl ester 
• 61426-49-1 (S)-2-bromo-cyclohex-2-en-1-ol 
• 97861-66-0 ethyl 2-bromo-2-cyclohexenyl carbonate 
• 117361-05-4 1-benzyloxy-2-bromo-2-cyclohexene 
• 198014-30-1 N-(2-Bromocyclohex-2-en-1-yl)-N-(2-nitrophenyl)methanesulfonamide 
• 850538-39-5 N-(R)-cyclohex-2-enyl-2-nitro-N-((S)-1-propylbut-3-enyl)benzenesulfonamide 
• 61426-49-1 (1R)-2-bromocyclohex-2-en-1-ol 
• 50870-61-6 2-bromocyclohex-2-en-1-one 
• 1542147-45-4 2-bromocyclohex-2-en-1-yl picolinate 
• 1637586-99-2 [3-(2-bromocyclohex-2-enyloxy)prop-1-ynyl]tert-butyldimethylsilane 
• 1637587-01-9 [4-(2-bromocyclohex-2-en-1-yloxy)but-2-yn-1-yloxy]tert-butyldimethylsilane 
• 1632352-26-1 (R)-2-bromocyclohex-2-en-1-yl diethyl phosphate 
• 1542147-92-1 (S)-6-bromo-1,2,3,4-tetrahydro-1,1'-biphenyl 

Relevant articles and documents

Overcoming equilibrium issues with carbonyl reductase enzymes

We report herein the screening, optimisation and scale up to 100 g of a bioreduction process that employs an in situ product removal (ISPR) technique to overcome the inherent equilibrium problem associated with the coupled-substrate approach to biocatalyt

Chemo-enzymatic synthesis of chiral cyclic compounds: Efficient kinetic resolution of 2-bromo-2-cyclohexenol

The kinetic resolution of 2-bromo-2-cyclohexenol has been achieved through enzyme-mediated transesterification in organic solvents, using vinyl acetate as the irreversible acylating agent. The effect of the enzyme and the solvent on the velocity and the enantioselectivity of the transformation has been studied. Also the influences of the size of the carbocyclic ring and the substituent in the 2-position have been briefly examined.

Synthesis of trans -2,6-disubstituted cyclohexanones through allylic substitution

trans-2,6-Disubstituted cyclohexanones were synthesized with high regio- and stereoselectivity by allylic substitution followed by ozonolysis. Both alkyl and aryl groups were successfully installed to the cyclohexane ring. The stereochemistry of the Ssub

Total synthesis of echinopines A and B

Eohinopines A and B [(+)-1 and (+)-2], two naturally occurring compounds characterized with a unique [3.5.5.7] carbon framework, have been synthesized In both enantiomeric and racemic forms. Their total synthesis Involves a novel intramolecular rhodium-catalyzed cyclopropanation (4 →16) and a samarium dilodide-medlated ring closure (3 → 37).