13772-59-3

Basic information

• Product Name: 3-Bromo-1-fluoronaphthalene
• Synonyms: 3-BROMO-1-FLUORONAPHTHALENE;3-BROMO-1-FLUORONAPHTHALENE,98+%(GC);1-fluoro-3-bromonaphthalene;3-Bromo-1-fluorophthalene
• CAS NO: 13772-59-3
• Molecular Formula: C₁₀H₆BrF
• Molecular Weight: 225.0570432
• Mol File: 13772-59-3.mol

Chemical Properties

• Boiling Point: 282.104 °C at 760 mmHg
• Flash Point: 128.005 °C
• Appearance: white solid powder
• Density: 1.564 g/cm³
• Vapor Pressure: 0.00584mmHg at 25°C
• Refractive Index: 1.638
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 3-Bromo-1-fluoronaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Bromo-1-fluoronaphthalene(13772-59-3)
• EPA Substance Registry System: 3-Bromo-1-fluoronaphthalene(13772-59-3)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 13772-59-3(Hazardous Substances Data)

Usage

Chemical Properties

white powder

InChI:InChI=1/C10H6BrF/c11-8-5-7-3-1-2-4-9(7)10(12)6-8/h1-6H

Upstream product

• 666732-19-0 C₁₀H₁₀BrFO₂ 
• 317-79-3 2-bromo-1-fluoronaphthalene 
• 438-32-4 4-Fluoro-1-aminonaphthalene 
• 90766-34-0 3-bromonaphthalen-1-amine 
• 341-92-4 1-fluoro-4-nitronaphthalene 
• 321-38-0 1-Fluoronaphthalene 

Downstream Products

• 874907-48-9 3-bromo-1-fluoro-2-iodonaphthalene 
• 182344-25-8 (4-fluoronaphthalen-1-yl)boronic acid 
• 34236-51-6 trans-1-(1-Fluor-3-naphthyl)-2-(o-jodphenyl)aethylen 
• 34236-50-5 trans-1-(1-Fluor-3-naphthyl)-2-phenylaethylen 
• 874907-58-1 1,1'-difluoro-3,3'-bis(diphenylphosphoryl)-2,2'-binaphthyl 
• 874907-57-0 (1-fluoronaphth-3-yl)diphenylphosphane oxide 

Relevant articles and documents

The abnormal behavior of an atropisomer: 3,3′-dibromo-1,1′- difluoro-2,2′-binaphthyl reacting with alkyllithium compounds

1-Fluoro-2-(triethylsilyl)naphthalene (1) and other 1-fluoronaphthalenes bearing a metalation-resistant substituent at the 2-position proved to be totally inert toward base attack. 3-Bromo-1-fluoronaphthalene (6), readily prepared from the 2-bromo isomer 5 by deprotonation-triggered heavy halogen migration, was converted into 3,3′-dibromo-1,1′-difluoro-2,2′- binaphthyl (8) by consecutive treatment with lithium diisopropylamide, copper(II) bromide and nitrobenzene. The dilithiated intermediate generated from the atropisomer 8 by treatment with 2 equiv. of butyllithium reacted with a variety of electrophiles to afford products such as the diacid 12 or the bis(phosphanes) 14 and 15 in high yields. The latter compound was also obtained in a straightforward manner from (4-fluoro-2-naphthyl)diphenylphosphane oxide (16). Unexpectedly, neither the 3,3′-dibromobinaphthyl 8 nor its 3,3′-diiodo analogue 18 were amenable to a unilateral but only to a double-sided halogen/metal permutation. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.

CYCLOPENTA[B]NAPHTHALENE DERIVATIVES

The invention relates to cyclopenta[b]naphthalene derivatives of general formula (I), where Z, A, n, R, L5, L6, (II) and (III) have the meanings defined in claim (1), the use thereof in liquid crystal or mesogenous media, liquid crystal or mesogenous media comprising at least one of said cyclopenta[b]naphthalene derivatives and electrooptical display elements comprising said liquid crystal or mesogenous media.