138833-06-4

Upstream product

• 140176-71-2 3,3-difluoro-3-phenyl-1(R)-<(4-methylphenyl)sulfinyl>-propan-2(S)-ol 
• 140176-52-9 (R)-3,3-difluoro-3-phenyl-1-<(4-methylphenyl)sulfinyl>-propan-2-one 
• 138833-03-1 benzyl 2,2-difluoro-2-phenylacetate 
• 140176-58-5 (2S)-2-(benzyloxy)-3,3-difluoro-3-phenyl-1(R)-<(4-methylphenyl)sulfinyl>propane 
• 100-39-0 benzyl bromide 

Downstream Products

• 140176-63-2 (R)-2-(benzyloxy)-3,3-difluoro-3-phenylpropanal N,N-dimethylhydrazone 
• 140176-65-4 (R)-N-1-<2-(benzyloxy)-3,3-difluoro-3-phenylpropyl>-O-benzylhydroxylamine 
• 138833-11-1 (R)-N-1-<2-(benzyloxy)-3,3-difluoro-3-phenylpropyl>-hydroxylamine 
• 138833-09-7 (R)-2-Benzyloxy-3,3-difluoro-3-phenyl-propionaldehyde oxime 
• 138833-08-6 (R)-2-(benzyloxy)-3,3-difluoro-3-phenylpropan-1-ol 
• 140176-69-8 (R,E)-2-(benzyloxy)-3,3-difluoro-3-phenylpropanal O-benzylamine 

Relevant academic research and scientific papers

Asymmetric Synthesis of Oxygen- and Nitrogen-Substituted Difluoromethylene Products

1,1-Difluoroalkyl sulfinylmethyl ketones 3 are synthesized in enantiomerically pure form through acylation of (+)-(R)-methyl p-tolyl sulfoxide (1) with α,α-difluorocarboxylates 2.These ketones have been reduced with complete diastereoselection to give the

A NEW ENTRY TO HOMOCHIRAL DIFLUORINATED COMPOUNDS

Some homochiral compounds containing a difluoromethylene unit along with oxygen and nitrogen functionalities have been obtained starting from α,α-difluorocarboxylic esters and (+)-(R)-methyl p-tolyl sulfoxide.