- Chemical Properties of 1,3,2-Diazaphospholines
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Δ4-1,3,2-Diazaphospholines exhibit properties typical of trivalent phosphorus derivatives: They take up sulfur, enter the Arbuzov, Perkow, and Staudinger reactions. On the other hand, these compounds show a number of peculiar features.
- Kibardin,Gryaznova,Pudovik
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p. 365 - 371
(2007/10/03)
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- SYNTHESIS AND SPECTRAL INVESTIGATION OF 2-CHLORO-1,3-DIBUTYL-4,5-DIMETHYL-Δ4-1,3,2-DIAZAPHOSPHOLINE
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2-Chloro-1,3-dibutyl-4,5-dimethyl-Δ4-1,3,2-diazaphospholine, which has an anomalously high boiling point, was obtained by reducing 2-ethoxy-1,3-dibutyl-4,5-dimethyl-Δ-1,3,2-diazaphospholine 2-oxide with trichlorosilane in the presence of a base.A complete spectral investigation was performed to confirm the structure of 2-chloro-1,3-dibutyl-4,5-dimethyl-Δ4-1,3,2-diazaphospholine and to elucidate the cause of the anomalies in its physical constants.
- Kibardin, A. M.,Gryaznova, T. V.,Zyablikova, T. A.,Latypov, Sh. K.,Musin, R. Z.,Pudovik, A. N.
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